η 3-furfuryl and η 3-thienyl complexes of palladium and platinum of relevance to the functionalization of biomass-derived furans

Yang Shi; Peter Brenner; Stefanie Bertsch; Krzysztof Radacki; Rian D. Dewhurst

doi:10.1021/om300568z

η ³-furfuryl and η ³-thienyl complexes of palladium and platinum of relevance to the functionalization of biomass-derived furans

Yang Shi, Peter Brenner, Stefanie Bertsch, Krzysztof Radacki, Rian D. Dewhurst^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A number of cationic and neutral η ³-furfuryl complexes of palladium and platinum were prepared, including one with a ligand derived from fructose, 5-chloromethylfurfural. The complexes were studied by variable-temperature and heteronuclear correlation NMR spectroscopy, as well as single-crystal X-ray crystallography. Analogous η ³-thienyl complexes could be prepared and detected in solution by NMR, but could not be isolated due to facile decomposition.

Original language	English
Pages (from-to)	5599-5605
Number of pages	7
Journal	Organometallics
Volume	31
Issue number	15
DOIs	https://doi.org/10.1021/om300568z
Publication status	Published - 13 Aug 2012
Externally published	Yes

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abstract = "A number of cationic and neutral η 3-furfuryl complexes of palladium and platinum were prepared, including one with a ligand derived from fructose, 5-chloromethylfurfural. The complexes were studied by variable-temperature and heteronuclear correlation NMR spectroscopy, as well as single-crystal X-ray crystallography. Analogous η 3-thienyl complexes could be prepared and detected in solution by NMR, but could not be isolated due to facile decomposition.",

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AU - Shi, Yang

AU - Brenner, Peter

AU - Bertsch, Stefanie

AU - Radacki, Krzysztof

AU - Dewhurst, Rian D.

PY - 2012/8/13

Y1 - 2012/8/13

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AB - A number of cationic and neutral η 3-furfuryl complexes of palladium and platinum were prepared, including one with a ligand derived from fructose, 5-chloromethylfurfural. The complexes were studied by variable-temperature and heteronuclear correlation NMR spectroscopy, as well as single-crystal X-ray crystallography. Analogous η 3-thienyl complexes could be prepared and detected in solution by NMR, but could not be isolated due to facile decomposition.

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ER -

η ³-furfuryl and η ³-thienyl complexes of palladium and platinum of relevance to the functionalization of biomass-derived furans

Abstract

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