[(μ-C){Re(CO)2(η-C5H5)} 2]: A surprisingly simple bimetallic carbido complex

Rowan D. Young; Anthony F. Hill; Germán E. Cavigliasso; Robert Stranger

doi:10.1002/anie.201207731

[(μ-C){Re(CO)₂(η-C₅H₅)} ₂]: A surprisingly simple bimetallic carbido complex

Rowan D. Young
, Anthony F. Hill^*
, Germán E. Cavigliasso
, Robert Stranger

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

It's easy to C: The reaction of [Re(CO)₂(CS)(η-C ₅H₅)] with [Re(CO)₂(thf)(η-C ₅H₅)] affords the disulfur complex [Re(CO) ₂(η²-S₂)(η-C₅H₅)] and the remarkably simple μ-carbido complex [(μ-C){Re(CO) ₂(η-C₅H₅)}₂], which has been structurally characterized and computationally investigated (see picture; black C, white H, red O, green Re).

Original language	English
Pages (from-to)	3699-3702
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	13
DOIs	https://doi.org/10.1002/anie.201207731
Publication status	Published - 25 Mar 2013

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title = "[(μ-C)\{Re(CO)2(η-C5H5)\} 2]: A surprisingly simple bimetallic carbido complex",

abstract = "It's easy to C: The reaction of [Re(CO)2(CS)(η-C 5H5)] with [Re(CO)2(thf)(η-C 5H5)] affords the disulfur complex [Re(CO) 2(η2-S2)(η-C5H5)] and the remarkably simple μ-carbido complex [(μ-C)\{Re(CO) 2(η-C5H5)\}2], which has been structurally characterized and computationally investigated (see picture; black C, white H, red O, green Re).",

keywords = "carbido complexes, metallacumulenes, rhenium, thiocarbonyl ligands",

author = "Young, \{Rowan D.\} and Hill, \{Anthony F.\} and Cavigliasso, \{Germ{\'a}n E.\} and Robert Stranger",

year = "2013",

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doi = "10.1002/anie.201207731",

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journal = "Angewandte Chemie - International Edition",

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T2 - A surprisingly simple bimetallic carbido complex

AU - Young, Rowan D.

AU - Hill, Anthony F.

AU - Cavigliasso, Germán E.

AU - Stranger, Robert

PY - 2013/3/25

Y1 - 2013/3/25

N2 - It's easy to C: The reaction of [Re(CO)2(CS)(η-C 5H5)] with [Re(CO)2(thf)(η-C 5H5)] affords the disulfur complex [Re(CO) 2(η2-S2)(η-C5H5)] and the remarkably simple μ-carbido complex [(μ-C){Re(CO) 2(η-C5H5)}2], which has been structurally characterized and computationally investigated (see picture; black C, white H, red O, green Re).

AB - It's easy to C: The reaction of [Re(CO)2(CS)(η-C 5H5)] with [Re(CO)2(thf)(η-C 5H5)] affords the disulfur complex [Re(CO) 2(η2-S2)(η-C5H5)] and the remarkably simple μ-carbido complex [(μ-C){Re(CO) 2(η-C5H5)}2], which has been structurally characterized and computationally investigated (see picture; black C, white H, red O, green Re).

KW - carbido complexes

KW - metallacumulenes

KW - rhenium

KW - thiocarbonyl ligands

UR - https://www.scopus.com/pages/publications/84875337042

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DO - 10.1002/anie.201207731

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EP - 3702

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 13

ER -

[(μ-C){Re(CO)₂(η-C₅H₅)} ₂]: A surprisingly simple bimetallic carbido complex

Abstract

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