1′-Trimethylsilylethynyl-, 1′-ethenyl- and 1′-formyl-1- ethynylferrocenes: Syntheses and electrochemical properties

Guillaume Grelaud; Gilles Argouarch; Marie P. Cifuentes; Mark G. Humphrey; Frédéric Paul

doi:10.1016/j.tet.2013.01.093

1′-Trimethylsilylethynyl-, 1′-ethenyl- and 1′-formyl-1- ethynylferrocenes: Syntheses and electrochemical properties

Guillaume Grelaud, Gilles Argouarch, Marie P. Cifuentes, Mark G. Humphrey^*, Frédéric Paul

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Efficient syntheses of 1′-trimethylsilylethynyl-, 1′-ethenyl-, and 1′-formyl-1-ethynylferrocenes are reported. The majority of these compounds exhibit chemically reversible ferrocene-based oxidation processes from cyclic voltammetry and thereby constitute key synthons for the development of redox-switchable molecular systems.

Original language	English
Pages (from-to)	3316-3322
Number of pages	7
Journal	Tetrahedron
Volume	69
Issue number	15
DOIs	https://doi.org/10.1016/j.tet.2013.01.093
Publication status	Published - 15 Apr 2013

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10.1016/j.tet.2013.01.093

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title = "1′-Trimethylsilylethynyl-, 1′-ethenyl- and 1′-formyl-1- ethynylferrocenes: Syntheses and electrochemical properties",

abstract = "Efficient syntheses of 1′-trimethylsilylethynyl-, 1′-ethenyl-, and 1′-formyl-1-ethynylferrocenes are reported. The majority of these compounds exhibit chemically reversible ferrocene-based oxidation processes from cyclic voltammetry and thereby constitute key synthons for the development of redox-switchable molecular systems.",

keywords = "1,1′-Functional ferrocenes, Cyclic voltammetry",

author = "Guillaume Grelaud and Gilles Argouarch and Cifuentes, \{Marie P.\} and Humphrey, \{Mark G.\} and Fr{\'e}d{\'e}ric Paul",

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AU - Grelaud, Guillaume

AU - Argouarch, Gilles

AU - Cifuentes, Marie P.

AU - Humphrey, Mark G.

AU - Paul, Frédéric

PY - 2013/4/15

Y1 - 2013/4/15

N2 - Efficient syntheses of 1′-trimethylsilylethynyl-, 1′-ethenyl-, and 1′-formyl-1-ethynylferrocenes are reported. The majority of these compounds exhibit chemically reversible ferrocene-based oxidation processes from cyclic voltammetry and thereby constitute key synthons for the development of redox-switchable molecular systems.

AB - Efficient syntheses of 1′-trimethylsilylethynyl-, 1′-ethenyl-, and 1′-formyl-1-ethynylferrocenes are reported. The majority of these compounds exhibit chemically reversible ferrocene-based oxidation processes from cyclic voltammetry and thereby constitute key synthons for the development of redox-switchable molecular systems.

KW - 1,1′-Functional ferrocenes

KW - Cyclic voltammetry

UR - https://www.scopus.com/pages/publications/84875227636

U2 - 10.1016/j.tet.2013.01.093

DO - 10.1016/j.tet.2013.01.093

M3 - Article

SN - 0040-4020

VL - 69

SP - 3316

EP - 3322

JO - Tetrahedron

JF - Tetrahedron

IS - 15

ER -

1′-Trimethylsilylethynyl-, 1′-ethenyl- and 1′-formyl-1- ethynylferrocenes: Syntheses and electrochemical properties

Abstract

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