7-Azaindol-7-ylborate: A novel bidentate N∧BH3 chelating ligand

Jörg Wagler; Anthony F. Hill

doi:10.1021/om700871p

7-Azaindol-7-ylborate: A novel bidentate N∧BH₃ chelating ligand

Jörg Wagler^*, Anthony F. Hill

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

7-Azaindole (H-azain) reacts with sodium borohydride (NaBH₄) to yield the sodium salt of the novel 7-azaindol7-ylborate anion (7-azain-7)BH ₃^-, two rhodium derivatives of which reveal distinct coordination modes -[Rh(κ²N,H-H₃B (7-azain-7)}(CO)(PPh₃)₂] and [Rh{κ³N,H, H′-H₃B(7-azain-7)} (PPh₃)₂]- thereby demonstrating how the variable denticity of the ligand may accommodate the varying electronic requirements of the metal center.

Original language	English
Pages (from-to)	2350-2353
Number of pages	4
Journal	Organometallics
Volume	27
Issue number	10
DOIs	https://doi.org/10.1021/om700871p
Publication status	Published - 26 May 2008

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@article{cd7d82dfe60542559357613a5a6cc447,

title = "7-Azaindol-7-ylborate: A novel bidentate N∧BH3 chelating ligand",

abstract = "7-Azaindole (H-azain) reacts with sodium borohydride (NaBH4) to yield the sodium salt of the novel 7-azaindol7-ylborate anion (7-azain-7)BH 3-, two rhodium derivatives of which reveal distinct coordination modes -[Rh(κ2N,H-H3B (7-azain-7)\}(CO)(PPh3)2] and [Rh\{κ3N,H, H′-H3B(7-azain-7)\} (PPh3)2]- thereby demonstrating how the variable denticity of the ligand may accommodate the varying electronic requirements of the metal center.",

author = "J{\"o}rg Wagler and Hill, \{Anthony F.\}",

year = "2008",

month = may,

day = "26",

doi = "10.1021/om700871p",

language = "English",

volume = "27",

pages = "2350--2353",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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TY - JOUR

T1 - 7-Azaindol-7-ylborate

T2 - A novel bidentate N∧BH3 chelating ligand

AU - Wagler, Jörg

AU - Hill, Anthony F.

PY - 2008/5/26

Y1 - 2008/5/26

N2 - 7-Azaindole (H-azain) reacts with sodium borohydride (NaBH4) to yield the sodium salt of the novel 7-azaindol7-ylborate anion (7-azain-7)BH 3-, two rhodium derivatives of which reveal distinct coordination modes -[Rh(κ2N,H-H3B (7-azain-7)}(CO)(PPh3)2] and [Rh{κ3N,H, H′-H3B(7-azain-7)} (PPh3)2]- thereby demonstrating how the variable denticity of the ligand may accommodate the varying electronic requirements of the metal center.

AB - 7-Azaindole (H-azain) reacts with sodium borohydride (NaBH4) to yield the sodium salt of the novel 7-azaindol7-ylborate anion (7-azain-7)BH 3-, two rhodium derivatives of which reveal distinct coordination modes -[Rh(κ2N,H-H3B (7-azain-7)}(CO)(PPh3)2] and [Rh{κ3N,H, H′-H3B(7-azain-7)} (PPh3)2]- thereby demonstrating how the variable denticity of the ligand may accommodate the varying electronic requirements of the metal center.

UR - https://www.scopus.com/pages/publications/44649114051

U2 - 10.1021/om700871p

DO - 10.1021/om700871p

M3 - Article

SN - 0276-7333

VL - 27

SP - 2350

EP - 2353

JO - Organometallics

JF - Organometallics

IS - 10

ER -

7-Azaindol-7-ylborate: A novel bidentate N∧BH₃ chelating ligand

Abstract

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