A (3 + 3)-dimensional "hypercubic" oxide-ionic conductor: Type II Bi2O3-Nb2O5

Chris D. Ling*, Siegbert Schmid, Peter E.R. Blanchard, Vaclav Petříček, Garry J. McIntyre, Neeraj Sharma, Andrey Maljuk, Aleksey A. Yaremchenko, Vladislav V. Kharton, Matthias Gutmann, Ray L. Withers

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    27 Citations (Scopus)

    Abstract

    The high-temperature cubic form of bismuth oxide, δ-Bi 2O3, is the best intermediate-temperature oxide-ionic conductor known. The most elegant way of stabilizing δ-Bi 2O3 to room temperature, while preserving a large part of its conductivity, is by doping with higher valent transition metals to create wide solid-solutions fields with exceedingly rare and complex (3 + 3)-dimensional incommensurately modulated "hypercubic" structures. These materials remain poorly understood because no such structure has ever been quantitatively solved and refined, due to both the complexity of the problem and a lack of adequate experimental data. We have addressed this by growing a large (centimeter scale) crystal using a novel refluxing floating-zone method, collecting high-quality single-crystal neutron diffraction data, and treating its structure together with X-ray diffraction data within the superspace symmetry formalism. The structure can be understood as an "inflated" pyrochlore, in which corner-connected NbO6 octahedral chains move smoothly apart to accommodate the solid solution. While some oxide vacancies are ordered into these chains, the rest are distributed throughout a continuous three-dimensional network of wide δ-Bi2O3-like channels, explaining the high oxide-ionic conductivity compared to commensurately modulated phases in the same pseudobinary system.

    Original languageEnglish
    Pages (from-to)6477-6484
    Number of pages8
    JournalJournal of the American Chemical Society
    Volume135
    Issue number17
    DOIs
    Publication statusPublished - 1 May 2013

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