A bidentate halogen-bonding bromoimidazoliophane receptor for bromide ion recognition in aqueous media

Antonio Caballero; Nicholas G. White; Paul D. Beer

doi:10.1002/anie.201006916

A bidentate halogen-bonding bromoimidazoliophane receptor for bromide ion recognition in aqueous media

Antonio Caballero^*, Nicholas G. White, Paul D. Beer

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

153 Citations (Scopus)

Abstract

A bidentate halogen-bonding bromoimidazoliophane receptor selectively binds bromide ions in competitive aqueous media (see picture, gray=carbon, blue=nitrogen, brown=bromine). The bromide ions are bound by cooperative convergent bromine atom/halogen-bonding halide anion interactions.

Original language	English
Pages (from-to)	1845-1848
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	8
DOIs	https://doi.org/10.1002/anie.201006916
Publication status	Published - 18 Feb 2011
Externally published	Yes

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title = "A bidentate halogen-bonding bromoimidazoliophane receptor for bromide ion recognition in aqueous media",

abstract = "A bidentate halogen-bonding bromoimidazoliophane receptor selectively binds bromide ions in competitive aqueous media (see picture, gray=carbon, blue=nitrogen, brown=bromine). The bromide ions are bound by cooperative convergent bromine atom/halogen-bonding halide anion interactions.",

keywords = "anions, halogenbonding, imidazoliophanes, receptors, supramolecular chemistry",

author = "Antonio Caballero and White, \{Nicholas G.\} and Beer, \{Paul D.\}",

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T1 - A bidentate halogen-bonding bromoimidazoliophane receptor for bromide ion recognition in aqueous media

AU - Caballero, Antonio

AU - White, Nicholas G.

AU - Beer, Paul D.

PY - 2011/2/18

Y1 - 2011/2/18

N2 - A bidentate halogen-bonding bromoimidazoliophane receptor selectively binds bromide ions in competitive aqueous media (see picture, gray=carbon, blue=nitrogen, brown=bromine). The bromide ions are bound by cooperative convergent bromine atom/halogen-bonding halide anion interactions.

AB - A bidentate halogen-bonding bromoimidazoliophane receptor selectively binds bromide ions in competitive aqueous media (see picture, gray=carbon, blue=nitrogen, brown=bromine). The bromide ions are bound by cooperative convergent bromine atom/halogen-bonding halide anion interactions.

KW - anions

KW - halogenbonding

KW - imidazoliophanes

KW - receptors

KW - supramolecular chemistry

UR - https://www.scopus.com/pages/publications/79951794843

U2 - 10.1002/anie.201006916

DO - 10.1002/anie.201006916

M3 - Article

SN - 1433-7851

VL - 50

SP - 1845

EP - 1848

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 8

ER -

A bidentate halogen-bonding bromoimidazoliophane receptor for bromide ion recognition in aqueous media

Abstract

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