Abstract
Successive treatment of [Mo(≡CBr)(CO)2{HB(pzMe 2)3}] (pz= pyrazol-1-yl) with "BuLi and mercuric chloride provides the bis(carbido)mercuriaÍ complex Hg[C=Mo(CO) 2{HB(pzMe2)3}]2, which is catalytically demercurated by [RhCl(CO)(PPh3)J to provide the bis-carbyne (ethanediylidyne) compound (μ-C2)[Mo(CO) 2{HB(pzMe2)3}]2.
Original language | English |
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Pages (from-to) | 4394-4399 |
Number of pages | 6 |
Journal | Organometallics |
Volume | 28 |
Issue number | 15 |
DOIs | |
Publication status | Published - 10 Aug 2009 |