A bis-carbyne (ethanediylidyne) complex via the catalytic demercuration of a mercury bis(carbido) complex

Annie L. Colebatch; Richard L. Cordiner; Anthony F. Hill; Kelly T.H.D. Nguyen; Rong Shang; Anthony C. Willis

doi:10.1021/om900462p

A bis-carbyne (ethanediylidyne) complex via the catalytic demercuration of a mercury bis(carbido) complex

Annie L. Colebatch, Richard L. Cordiner, Anthony F. Hill, Kelly T.H.D. Nguyen, Rong Shang, Anthony C. Willis

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

Successive treatment of [Mo(≡CBr)(CO)₂{HB(pzMe ₂)₃}] (pz= pyrazol-1-yl) with "BuLi and mercuric chloride provides the bis(carbido)mercuriaÍ complex Hg[C=Mo(CO) ₂{HB(pzMe₂)₃}]₂, which is catalytically demercurated by [RhCl(CO)(PPh₃)J to provide the bis-carbyne (ethanediylidyne) compound (μ-C₂)[Mo(CO) ₂{HB(pzMe₂)₃}]₂.

Original language	English
Pages (from-to)	4394-4399
Number of pages	6
Journal	Organometallics
Volume	28
Issue number	15
DOIs	https://doi.org/10.1021/om900462p
Publication status	Published - 10 Aug 2009

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title = "A bis-carbyne (ethanediylidyne) complex via the catalytic demercuration of a mercury bis(carbido) complex",

abstract = "Successive treatment of [Mo(≡CBr)(CO)2\{HB(pzMe 2)3\}] (pz= pyrazol-1-yl) with {"}BuLi and mercuric chloride provides the bis(carbido)mercuria{\'I} complex Hg[C=Mo(CO) 2\{HB(pzMe2)3\}]2, which is catalytically demercurated by [RhCl(CO)(PPh3)J to provide the bis-carbyne (ethanediylidyne) compound (μ-C2)[Mo(CO) 2\{HB(pzMe2)3\}]2.",

author = "Colebatch, \{Annie L.\} and Cordiner, \{Richard L.\} and Hill, \{Anthony F.\} and Nguyen, \{Kelly T.H.D.\} and Rong Shang and Willis, \{Anthony C.\}",

year = "2009",

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doi = "10.1021/om900462p",

language = "English",

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T1 - A bis-carbyne (ethanediylidyne) complex via the catalytic demercuration of a mercury bis(carbido) complex

AU - Colebatch, Annie L.

AU - Cordiner, Richard L.

AU - Hill, Anthony F.

AU - Nguyen, Kelly T.H.D.

AU - Shang, Rong

AU - Willis, Anthony C.

PY - 2009/8/10

Y1 - 2009/8/10

N2 - Successive treatment of [Mo(≡CBr)(CO)2{HB(pzMe 2)3}] (pz= pyrazol-1-yl) with "BuLi and mercuric chloride provides the bis(carbido)mercuriaÍ complex Hg[C=Mo(CO) 2{HB(pzMe2)3}]2, which is catalytically demercurated by [RhCl(CO)(PPh3)J to provide the bis-carbyne (ethanediylidyne) compound (μ-C2)[Mo(CO) 2{HB(pzMe2)3}]2.

AB - Successive treatment of [Mo(≡CBr)(CO)2{HB(pzMe 2)3}] (pz= pyrazol-1-yl) with "BuLi and mercuric chloride provides the bis(carbido)mercuriaÍ complex Hg[C=Mo(CO) 2{HB(pzMe2)3}]2, which is catalytically demercurated by [RhCl(CO)(PPh3)J to provide the bis-carbyne (ethanediylidyne) compound (μ-C2)[Mo(CO) 2{HB(pzMe2)3}]2.

UR - https://www.scopus.com/pages/publications/68149124393

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DO - 10.1021/om900462p

M3 - Article

SN - 0276-7333

VL - 28

SP - 4394

EP - 4399

JO - Organometallics

JF - Organometallics

IS - 15

ER -

A bis-carbyne (ethanediylidyne) complex via the catalytic demercuration of a mercury bis(carbido) complex

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