Abstract
The fluoride-mediated protodesilylation of [W(≡CC≡CSiMe 3)(CO)2{HB(pz)3}](pz = pyrazol-1-yl) in the presence of Vaska's complex provides the first bis-(tricarbido) trimetallic complex, [IrH(C≡CC≡W(CO)2-{HB(pz)3}) 2(CO)(PPh3)2], the crystal structure of which reveals a linear nine-membered WC3IrC3W chain.
Original language | English |
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Pages (from-to) | 1646-1648 |
Number of pages | 3 |
Journal | Organometallics |
Volume | 23 |
Issue number | 8 |
DOIs | |
Publication status | Published - 12 Apr 2004 |