A Bis(tricarbido) Complex of Iridium and Tungsten: [IrH(C≡CC≡W(CO)2{HB(pz)3})2(CO) (PPh3)2]

Rian D. Dewhurst, Anthony F. Hill*, Anthony C. Willis

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    27 Citations (Scopus)

    Abstract

    The fluoride-mediated protodesilylation of [W(≡CC≡CSiMe 3)(CO)2{HB(pz)3}](pz = pyrazol-1-yl) in the presence of Vaska's complex provides the first bis-(tricarbido) trimetallic complex, [IrH(C≡CC≡W(CO)2-{HB(pz)3}) 2(CO)(PPh3)2], the crystal structure of which reveals a linear nine-membered WC3IrC3W chain.

    Original languageEnglish
    Pages (from-to)1646-1648
    Number of pages3
    JournalOrganometallics
    Volume23
    Issue number8
    DOIs
    Publication statusPublished - 12 Apr 2004

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