A Bis(tricarbido) Complex of Iridium and Tungsten: [IrH(C≡CC≡W(CO)2{HB(pz)3})2(CO) (PPh3)2]

Rian D. Dewhurst; Anthony F. Hill; Anthony C. Willis

doi:10.1021/om0306877

A Bis(tricarbido) Complex of Iridium and Tungsten: [IrH(C≡CC≡W(CO)₂{HB(pz)₃})₂(CO) (PPh₃)₂]

Rian D. Dewhurst, Anthony F. Hill^*, Anthony C. Willis

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

The fluoride-mediated protodesilylation of [W(≡CC≡CSiMe ₃)(CO)₂{HB(pz)₃}](pz = pyrazol-1-yl) in the presence of Vaska's complex provides the first bis-(tricarbido) trimetallic complex, [IrH(C≡CC≡W(CO)₂-{HB(pz)₃}) ₂(CO)(PPh₃)₂], the crystal structure of which reveals a linear nine-membered WC₃IrC₃W chain.

Original language	English
Pages (from-to)	1646-1648
Number of pages	3
Journal	Organometallics
Volume	23
Issue number	8
DOIs	https://doi.org/10.1021/om0306877
Publication status	Published - 12 Apr 2004

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title = "A Bis(tricarbido) Complex of Iridium and Tungsten: [IrH(C≡CC≡W(CO)2\{HB(pz)3\})2(CO) (PPh3)2]",

abstract = "The fluoride-mediated protodesilylation of [W(≡CC≡CSiMe 3)(CO)2\{HB(pz)3\}](pz = pyrazol-1-yl) in the presence of Vaska's complex provides the first bis-(tricarbido) trimetallic complex, [IrH(C≡CC≡W(CO)2-\{HB(pz)3\}) 2(CO)(PPh3)2], the crystal structure of which reveals a linear nine-membered WC3IrC3W chain.",

author = "Dewhurst, \{Rian D.\} and Hill, \{Anthony F.\} and Willis, \{Anthony C.\}",

year = "2004",

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day = "12",

doi = "10.1021/om0306877",

language = "English",

volume = "23",

pages = "1646--1648",

journal = "Organometallics",

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publisher = "American Chemical Society",

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T1 - A Bis(tricarbido) Complex of Iridium and Tungsten

T2 - [IrH(C≡CC≡W(CO)2{HB(pz)3})2(CO) (PPh3)2]

AU - Dewhurst, Rian D.

AU - Hill, Anthony F.

AU - Willis, Anthony C.

PY - 2004/4/12

Y1 - 2004/4/12

N2 - The fluoride-mediated protodesilylation of [W(≡CC≡CSiMe 3)(CO)2{HB(pz)3}](pz = pyrazol-1-yl) in the presence of Vaska's complex provides the first bis-(tricarbido) trimetallic complex, [IrH(C≡CC≡W(CO)2-{HB(pz)3}) 2(CO)(PPh3)2], the crystal structure of which reveals a linear nine-membered WC3IrC3W chain.

AB - The fluoride-mediated protodesilylation of [W(≡CC≡CSiMe 3)(CO)2{HB(pz)3}](pz = pyrazol-1-yl) in the presence of Vaska's complex provides the first bis-(tricarbido) trimetallic complex, [IrH(C≡CC≡W(CO)2-{HB(pz)3}) 2(CO)(PPh3)2], the crystal structure of which reveals a linear nine-membered WC3IrC3W chain.

UR - https://www.scopus.com/pages/publications/2342434015

U2 - 10.1021/om0306877

DO - 10.1021/om0306877

M3 - Article

SN - 0276-7333

VL - 23

SP - 1646

EP - 1648

JO - Organometallics

JF - Organometallics

IS - 8

ER -

A Bis(tricarbido) Complex of Iridium and Tungsten: [IrH(C≡CC≡W(CO)₂{HB(pz)₃})₂(CO) (PPh₃)₂]

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