A bridging selenoacyl complex via alkynylselenolatoalkylidyne rearrangement

Lorraine M. Caldwell, Richard L. Cordiner, Anthony F. Hill, Jörg Wagler

    Research output: Contribution to journalArticlepeer-review

    25 Citations (Scopus)

    Abstract

    The alkynylselenolatoalkylidyne complex [Mo(-C-Se-C-CSiMe 3)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) reacts with [RhCl(PPh3)3] via an unusual C-Se bond cleavage/formation sequence to provide the heterodinuclear bridging selenoacyl complex [MoRh(μ--SeCC-CSiMe3)Cl(CO) 2(PPh3){HB(pzMe2)3}], the crystal structure of which reveals a RhMoCSe tetrahedrane core.

    Original languageEnglish
    Pages (from-to)1526-1529
    Number of pages4
    JournalOrganometallics
    Volume29
    Issue number7
    DOIs
    Publication statusPublished - 12 Apr 2010

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