A bridging selenoacyl complex via alkynylselenolatoalkylidyne rearrangement

Lorraine M. Caldwell; Richard L. Cordiner; Anthony F. Hill; Jörg Wagler

doi:10.1021/om901079n

A bridging selenoacyl complex via alkynylselenolatoalkylidyne rearrangement

Lorraine M. Caldwell, Richard L. Cordiner, Anthony F. Hill, Jörg Wagler

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

The alkynylselenolatoalkylidyne complex [Mo(-C-Se-C-CSiMe ₃)(CO)₂{HB(pzMe₂)₃}] (pz = pyrazol-1-yl) reacts with [RhCl(PPh₃)₃] via an unusual C-Se bond cleavage/formation sequence to provide the heterodinuclear bridging selenoacyl complex [MoRh(μ_--SeCC-CSiMe₃)Cl(CO) ₂(PPh₃){HB(pzMe₂)₃}], the crystal structure of which reveals a RhMoCSe tetrahedrane core.

Original language	English
Pages (from-to)	1526-1529
Number of pages	4
Journal	Organometallics
Volume	29
Issue number	7
DOIs	https://doi.org/10.1021/om901079n
Publication status	Published - 12 Apr 2010

Access to Document

10.1021/om901079n

Cite this

@article{c9b9e88e82704d47aa0278be8f340d5b,

title = "A bridging selenoacyl complex via alkynylselenolatoalkylidyne rearrangement",

abstract = "The alkynylselenolatoalkylidyne complex [Mo(-C-Se-C-CSiMe 3)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) reacts with [RhCl(PPh3)3] via an unusual C-Se bond cleavage/formation sequence to provide the heterodinuclear bridging selenoacyl complex [MoRh(μ--SeCC-CSiMe3)Cl(CO) 2(PPh3){HB(pzMe2)3}], the crystal structure of which reveals a RhMoCSe tetrahedrane core.",

author = "Caldwell, {Lorraine M.} and Cordiner, {Richard L.} and Hill, {Anthony F.} and J{\"o}rg Wagler",

year = "2010",

month = apr,

day = "12",

doi = "10.1021/om901079n",

language = "English",

volume = "29",

pages = "1526--1529",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "7",

}

TY - JOUR

T1 - A bridging selenoacyl complex via alkynylselenolatoalkylidyne rearrangement

AU - Caldwell, Lorraine M.

AU - Cordiner, Richard L.

AU - Hill, Anthony F.

AU - Wagler, Jörg

PY - 2010/4/12

Y1 - 2010/4/12

N2 - The alkynylselenolatoalkylidyne complex [Mo(-C-Se-C-CSiMe 3)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) reacts with [RhCl(PPh3)3] via an unusual C-Se bond cleavage/formation sequence to provide the heterodinuclear bridging selenoacyl complex [MoRh(μ--SeCC-CSiMe3)Cl(CO) 2(PPh3){HB(pzMe2)3}], the crystal structure of which reveals a RhMoCSe tetrahedrane core.

AB - The alkynylselenolatoalkylidyne complex [Mo(-C-Se-C-CSiMe 3)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) reacts with [RhCl(PPh3)3] via an unusual C-Se bond cleavage/formation sequence to provide the heterodinuclear bridging selenoacyl complex [MoRh(μ--SeCC-CSiMe3)Cl(CO) 2(PPh3){HB(pzMe2)3}], the crystal structure of which reveals a RhMoCSe tetrahedrane core.

UR - http://www.scopus.com/inward/record.url?scp=77950824629&partnerID=8YFLogxK

U2 - 10.1021/om901079n

DO - 10.1021/om901079n

M3 - Article

SN - 0276-7333

VL - 29

SP - 1526

EP - 1529

JO - Organometallics

JF - Organometallics

IS - 7

ER -

A bridging selenoacyl complex via alkynylselenolatoalkylidyne rearrangement

Abstract

Access to Document

Other files and links

Fingerprint

Cite this