Abstract
The synthesis of the D-talose derivatives from the readily available and enantiomerically pure cis-1,2-dihydrocatechol was discussed. The synthesis included a stannylene acetal-mediated epimerization process. The dehydroxylation of D-galactal provided a different route to target. The triacetates were chemically correlated with known derivatives of D-talose. A mixture of these compounds was also subjected to reaction with aqueous trifluoroacetic acid to affect global deprotection and generate D-talose.
Original language | English |
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Pages (from-to) | 95-103 |
Number of pages | 9 |
Journal | Australian Journal of Chemistry |
Volume | 55 |
Issue number | 1-2 |
DOIs | |
Publication status | Published - 2002 |