A complete set of pnictocarbynes: [M(CAPh2)(CO)2(Tp∗)] (M = Mo, W; A = N, P, As, Sb, Bi; Tp∗ = hydrotris(dimethylpyrazolyl)-borate)

Benjamin J. Frogley; Anthony F. Hill

doi:10.1039/c8cc00143j

A complete set of pnictocarbynes: [M(CAPh₂)(CO)₂(Tp∗)] (M = Mo, W; A = N, P, As, Sb, Bi; Tp∗ = hydrotris(dimethylpyrazolyl)-borate)

Benjamin J. Frogley
, Anthony F. Hill

The Australian National University

Research output: Contribution to journal › Literature review › peer-review

22 Citations (Scopus)

Abstract

The first two complete series of pnictogen functionalised carbyne complexes, [M(CAPh₂)(CO)₂(Tp∗)] (M = Mo, W; A = N, P, As, Sb, Bi; Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate), have been prepared. The heavier analogues (A ≠ N) result from successive treatment of [M(CBr)(CO)₂(Tp∗)] with ⁿBuLi and ClAPPh₂ (A = P, Sb, Bi) or BrAsPh₂ and include the first examples of arsino, stibino or bismuthino carbyne complexes.

Original language	English
Pages (from-to)	2126-2129
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	17
DOIs	https://doi.org/10.1039/c8cc00143j https://doi.org/10.1039/c8cc00143j
Publication status	Published - 2018

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title = "A complete set of pnictocarbynes: [M(CAPh2)(CO)2(Tp∗)] (M = Mo, W; A = N, P, As, Sb, Bi; Tp∗ = hydrotris(dimethylpyrazolyl)-borate)",

abstract = "The first two complete series of pnictogen functionalised carbyne complexes, [M(CAPh2)(CO)2(Tp∗)] (M = Mo, W; A = N, P, As, Sb, Bi; Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate), have been prepared. The heavier analogues (A ≠ N) result from successive treatment of [M(CBr)(CO)2(Tp∗)] with nBuLi and ClAPPh2 (A = P, Sb, Bi) or BrAsPh2 and include the first examples of arsino, stibino or bismuthino carbyne complexes.",

keywords = "Metal-carbon bonds, Carbyne complexes, Alkylidyne complexes, Phosphoniocarbyne complexes, Aminocarbyne complexes, Tungsten, Pyrazol-1-yl, Molybdenum, Chemistry, Coordination",

author = "Frogley, \{Benjamin J.\} and Hill, \{Anthony F.\}",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c8cc00143j",

language = "English",

volume = "54",

pages = "2126--2129",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "17",

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T1 - A complete set of pnictocarbynes

T2 - [M(CAPh2)(CO)2(Tp∗)] (M = Mo, W; A = N, P, As, Sb, Bi; Tp∗ = hydrotris(dimethylpyrazolyl)-borate)

AU - Frogley, Benjamin J.

AU - Hill, Anthony F.

PY - 2018

Y1 - 2018

N2 - The first two complete series of pnictogen functionalised carbyne complexes, [M(CAPh2)(CO)2(Tp∗)] (M = Mo, W; A = N, P, As, Sb, Bi; Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate), have been prepared. The heavier analogues (A ≠ N) result from successive treatment of [M(CBr)(CO)2(Tp∗)] with nBuLi and ClAPPh2 (A = P, Sb, Bi) or BrAsPh2 and include the first examples of arsino, stibino or bismuthino carbyne complexes.

AB - The first two complete series of pnictogen functionalised carbyne complexes, [M(CAPh2)(CO)2(Tp∗)] (M = Mo, W; A = N, P, As, Sb, Bi; Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate), have been prepared. The heavier analogues (A ≠ N) result from successive treatment of [M(CBr)(CO)2(Tp∗)] with nBuLi and ClAPPh2 (A = P, Sb, Bi) or BrAsPh2 and include the first examples of arsino, stibino or bismuthino carbyne complexes.

KW - Metal-carbon bonds

KW - Carbyne complexes

KW - Alkylidyne complexes

KW - Phosphoniocarbyne complexes

KW - Aminocarbyne complexes

KW - Tungsten

KW - Pyrazol-1-yl

KW - Molybdenum

KW - Chemistry

KW - Coordination

UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:000428549200012&DestLinkType=FullRecord&DestApp=WOS_CPL

U2 - 10.1039/c8cc00143j

DO - 10.1039/c8cc00143j

M3 - Literature review

C2 - 29419834

SN - 1359-7345

VL - 54

SP - 2126

EP - 2129

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

A complete set of pnictocarbynes: [M(CAPh₂)(CO)₂(Tp∗)] (M = Mo, W; A = N, P, As, Sb, Bi; Tp∗ = hydrotris(dimethylpyrazolyl)-borate)

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Heteroatomic Organometallic Molecular Wires

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A complete set of pnictocarbynes: [M(CAPh2)(CO)2(Tp∗)] (M = Mo, W; A = N, P, As, Sb, Bi; Tp∗ = hydrotris(dimethylpyrazolyl)-borate)

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A complete set of pnictocarbynes: [M(CAPh₂)(CO)₂(Tp∗)] (M = Mo, W; A = N, P, As, Sb, Bi; Tp∗ = hydrotris(dimethylpyrazolyl)-borate)