A density functional theory study of π-facial stereoselectivity in intramolecular Diels-Alder reactions

M. N. Paddon-Row; M. S. Sherburn

doi:10.1039/b006486f

A density functional theory study of π-facial stereoselectivity in intramolecular Diels-Alder reactions

M. N. Paddon-Row^*, M. S. Sherburn

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

B3LYP/6-31G(d) theory has been used to construct a transition structure model which correctly accounts for the observed π-diastereofacial selectivity in intramolecular Diels-Alder reactions induced by allylic substituents attached to the diene.

Original language	English
Pages (from-to)	2215-2216
Number of pages	2
Journal	Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/b006486f
Publication status	Published - 21 Nov 2000
Externally published	Yes

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title = "A density functional theory study of π-facial stereoselectivity in intramolecular Diels-Alder reactions",

abstract = "B3LYP/6-31G(d) theory has been used to construct a transition structure model which correctly accounts for the observed π-diastereofacial selectivity in intramolecular Diels-Alder reactions induced by allylic substituents attached to the diene.",

author = "Paddon-Row, \{M. N.\} and Sherburn, \{M. S.\}",

year = "2000",

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A density functional theory study of π-facial stereoselectivity in intramolecular Diels-Alder reactions

Abstract

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