A diazoalkane complex of titanium

Lawrence B. Kool; Marvin D. Rausch; Helmut G. Alt; Max Herberhold; Anthony F. Hill; Ulf Thewalt; Brigitte Wolf

doi:10.1039/C39860000408

A diazoalkane complex of titanium

Lawrence B. Kool^*
, Marvin D. Rausch
, Helmut G. Alt
, Max Herberhold
, Anthony F. Hill
, Ulf Thewalt
, Brigitte Wolf

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

(cp)₂Ti(PMe₃)₂ (cp=η⁵- C₅H₅) and (cp)₂Ti(CO)(PMe₃) react with diphenyldiazomethane to yield (cp)₂Ti(NNCPh₂) (PMe₃), the crystal structure of which has been determined, containing a monodentate diazoalkane ligand end-on co-ordinated through nitrogen.

Original language	English
Pages (from-to)	408-409
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/C39860000408
Publication status	Published - 1986
Externally published	Yes

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title = "A diazoalkane complex of titanium",

abstract = "(cp)2Ti(PMe3)2 (cp=η5- C5H5) and (cp)2Ti(CO)(PMe3) react with diphenyldiazomethane to yield (cp)2Ti(NNCPh2) (PMe3), the crystal structure of which has been determined, containing a monodentate diazoalkane ligand end-on co-ordinated through nitrogen.",

author = "Kool, \{Lawrence B.\} and Rausch, \{Marvin D.\} and Alt, \{Helmut G.\} and Max Herberhold and Hill, \{Anthony F.\} and Ulf Thewalt and Brigitte Wolf",

year = "1986",

doi = "10.1039/C39860000408",

language = "English",

pages = "408--409",

journal = "Journal of the Chemical Society D: Chemical Communications",

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T1 - A diazoalkane complex of titanium

AU - Kool, Lawrence B.

AU - Rausch, Marvin D.

AU - Alt, Helmut G.

AU - Herberhold, Max

AU - Hill, Anthony F.

AU - Thewalt, Ulf

AU - Wolf, Brigitte

PY - 1986

Y1 - 1986

N2 - (cp)2Ti(PMe3)2 (cp=η5- C5H5) and (cp)2Ti(CO)(PMe3) react with diphenyldiazomethane to yield (cp)2Ti(NNCPh2) (PMe3), the crystal structure of which has been determined, containing a monodentate diazoalkane ligand end-on co-ordinated through nitrogen.

AB - (cp)2Ti(PMe3)2 (cp=η5- C5H5) and (cp)2Ti(CO)(PMe3) react with diphenyldiazomethane to yield (cp)2Ti(NNCPh2) (PMe3), the crystal structure of which has been determined, containing a monodentate diazoalkane ligand end-on co-ordinated through nitrogen.

UR - https://www.scopus.com/pages/publications/37049084993

U2 - 10.1039/C39860000408

DO - 10.1039/C39860000408

M3 - Article

AN - SCOPUS:37049084993

SN - 0022-4936

SP - 408

EP - 409

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 5

ER -

A diazoalkane complex of titanium

Abstract

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