A dichlorido-bridged dinuclear Dy(III) single-molecule magnet with an effective energy barrier larger than 600 K

Tian Han; You-Song Ding; Zi-Han Li; Ke-Xin Yu; Yuan-Qi Zhai; Nicholas F. Chilton; Yan-Zhen Zheng

doi:10.1039/C9CC02436K

A dichlorido-bridged dinuclear Dy(III) single-molecule magnet with an effective energy barrier larger than 600 K

Tian Han, You-Song Ding, Zi-Han Li, Ke-Xin Yu, Yuan-Qi Zhai, Nicholas F. Chilton^*, Yan-Zhen Zheng^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

51 Citations (Scopus)

Abstract

We report a dichlorido-bridged dinuclear dysprosium(III) single-molecule magnet [Dy(Cy₂N)₂(μ-Cl)(THF)]₂ which shows an effective energy barrier for magnetization reversal (U_eff) of ca. 623 K. This is by far the largest U_effbarrier for any chlorido-bridged lanthanide single-molecule magnet. We observe two relaxation processes with near-identical temperature dependencies, one of which disappears upon magnetic dilution. We suspect that these two processes are the isolated and coupled relaxation processes.

Original language	English
Pages (from-to)	7930-7933
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	55
DOIs	https://doi.org/10.1039/C9CC02436K
Publication status	Published - 12 Jun 2019
Externally published	Yes

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title = "A dichlorido-bridged dinuclear Dy(III) single-molecule magnet with an effective energy barrier larger than 600 K",

abstract = "We report a dichlorido-bridged dinuclear dysprosium(III) single-molecule magnet [Dy(Cy2N)2(μ-Cl)(THF)]2 which shows an effective energy barrier for magnetization reversal (Ueff) of ca. 623 K. This is by far the largest Ueff barrier for any chlorido-bridged lanthanide single-molecule magnet. We observe two relaxation processes with near-identical temperature dependencies, one of which disappears upon magnetic dilution. We suspect that these two processes are the isolated and coupled relaxation processes.",

author = "Tian Han and You-Song Ding and Zi-Han Li and Ke-Xin Yu and Yuan-Qi Zhai and Chilton, \{Nicholas F.\} and Yan-Zhen Zheng",

year = "2019",

month = jun,

day = "12",

doi = "10.1039/C9CC02436K",

language = "English",

volume = "55",

pages = "7930--7933",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - A dichlorido-bridged dinuclear Dy(III) single-molecule magnet with an effective energy barrier larger than 600 K

AU - Han, Tian

AU - Ding, You-Song

AU - Li, Zi-Han

AU - Yu, Ke-Xin

AU - Zhai, Yuan-Qi

AU - Chilton, Nicholas F.

AU - Zheng, Yan-Zhen

PY - 2019/6/12

Y1 - 2019/6/12

N2 - We report a dichlorido-bridged dinuclear dysprosium(III) single-molecule magnet [Dy(Cy2N)2(μ-Cl)(THF)]2 which shows an effective energy barrier for magnetization reversal (Ueff) of ca. 623 K. This is by far the largest Ueff barrier for any chlorido-bridged lanthanide single-molecule magnet. We observe two relaxation processes with near-identical temperature dependencies, one of which disappears upon magnetic dilution. We suspect that these two processes are the isolated and coupled relaxation processes.

AB - We report a dichlorido-bridged dinuclear dysprosium(III) single-molecule magnet [Dy(Cy2N)2(μ-Cl)(THF)]2 which shows an effective energy barrier for magnetization reversal (Ueff) of ca. 623 K. This is by far the largest Ueff barrier for any chlorido-bridged lanthanide single-molecule magnet. We observe two relaxation processes with near-identical temperature dependencies, one of which disappears upon magnetic dilution. We suspect that these two processes are the isolated and coupled relaxation processes.

UR - https://www.scopus.com/pages/publications/85068579849

U2 - 10.1039/C9CC02436K

DO - 10.1039/C9CC02436K

M3 - Article

SN - 1359-7345

VL - 55

SP - 7930

EP - 7933

JO - Chemical Communications

JF - Chemical Communications

IS - 55

ER -

A dichlorido-bridged dinuclear Dy(III) single-molecule magnet with an effective energy barrier larger than 600 K

Abstract

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