Abstract
The linear μ-carbido complex [Rh2(μ-C)Cl2(dppm)2] (dppm=bis(diphenylphosphino)methane) reacts with dimethylacetylene dicarboxylate (DMAD) to afford [Rh2(μ-C)(μ-DMAD)Cl2(dppm)2], which features a bent RhCRh linkage (124.7°) that might be described as a dirhoda-heterocyclic carbene, as demonstrated by coordination to further metal centers.
Original language | English |
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Pages (from-to) | 4274-4277 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 59 |
Issue number | 11 |
DOIs | |
Publication status | Published - 9 Mar 2020 |