A dynamic covalent approach to [PtnL2n]2n+ cages

Quinn V.C. van Hilst; Aston C. Pearcy; Dan Preston; L. James Wright; Christian G. Hartinger; Heather J.L. Brooks; James D. Crowley

doi:10.1039/d4cc00323c

A dynamic covalent approach to [Pt_nL_2n]²ⁿ⁺ cages

Quinn V.C. van Hilst, Aston C. Pearcy, Dan Preston, L. James Wright, Christian G. Hartinger, Heather J.L. Brooks, James D. Crowley^*

^*Corresponding author for this work

Research School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A dynamic covalent approach was exploited to generate a family of homometallic [Pt_nL_2n]²ⁿ⁺ cage (predominantly [Pt₂L₄]⁴⁺ systems) architectures. The family of platinum(ii) architectures were characterized using ¹H nuclear magnetic resonance (NMR) and diffusion ordered spectroscopy (DOSY), electrospray ionization mass spectrometry (ESI-MS) and the molecular structures of two cages were determined by X-ray crystallography.

Original language	English
Pages (from-to)	4302-4305
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	32
DOIs	https://doi.org/10.1039/d4cc00323c
Publication status	Published - 20 Mar 2024

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title = "A dynamic covalent approach to [PtnL2n]2n+ cages",

abstract = "A dynamic covalent approach was exploited to generate a family of homometallic [PtnL2n]2n+ cage (predominantly [Pt2L4]4+ systems) architectures. The family of platinum(ii) architectures were characterized using 1H nuclear magnetic resonance (NMR) and diffusion ordered spectroscopy (DOSY), electrospray ionization mass spectrometry (ESI-MS) and the molecular structures of two cages were determined by X-ray crystallography.",

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AU - van Hilst, Quinn V.C.

AU - Pearcy, Aston C.

AU - Preston, Dan

AU - Wright, L. James

AU - Hartinger, Christian G.

AU - Brooks, Heather J.L.

AU - Crowley, James D.

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AB - A dynamic covalent approach was exploited to generate a family of homometallic [PtnL2n]2n+ cage (predominantly [Pt2L4]4+ systems) architectures. The family of platinum(ii) architectures were characterized using 1H nuclear magnetic resonance (NMR) and diffusion ordered spectroscopy (DOSY), electrospray ionization mass spectrometry (ESI-MS) and the molecular structures of two cages were determined by X-ray crystallography.

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JF - Chemical Communications

IS - 32

ER -

A dynamic covalent approach to [Pt_nL_2n]²ⁿ⁺ cages

Abstract

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