A ferrocene imidazolium-based macrocycle as an electrochemical chemosensor for halide anions

Antonio Caballero; Nicholas G. White; Paul D. Beer

doi:10.1039/c3ce41851k

A ferrocene imidazolium-based macrocycle as an electrochemical chemosensor for halide anions

Antonio Caballero, Nicholas G. White, Paul D. Beer^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

C4-H and C5-H protons of the imidazolium heterocycle have been exploited as a binding site for anion recognition in the design of two new redox-active imidazoliophane syn and anti isomers. The cooperative action of the two imidazolium motifs of the syn isomer is crucial for halide anion recognition. The integration of a ferrocene signalling unit at the C2 position of the imidazolium motif also facilitates the electrochemical sensing of anions by the syn isomer receptor. This journal is

Original language	English
Pages (from-to)	3694-3698
Number of pages	5
Journal	CrystEngComm
Volume	16
Issue number	18
DOIs	https://doi.org/10.1039/c3ce41851k
Publication status	Published - 14 May 2014
Externally published	Yes

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A ferrocene imidazolium-based macrocycle as an electrochemical chemosensor for halide anions

Abstract

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