A fresh approach to voltammetric modelling

Peter J. Mahon; Jan C. Myland; Keith B. Oldham

doi:10.1016/S0022-0728(02)01263-9

A fresh approach to voltammetric modelling

Peter J. Mahon, Jan C. Myland, Keith B. Oldham^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

A modular semianalytic procedure, alternative to simulation, is described for predicting the transient current response to any applied potential signal under a wide variety of voltammetric conditions. Diverse geometries may be treated; the electrode reaction may have any degree of reversibility; homogeneous chemical reactions may be involved. Conceptually, the method consists of splitting the overall problem into three components, each of which is solved separately. Examples presented include cyclic voltammetry and (Osteryoung) square-wave voltammetry.

Original language	English
Pages (from-to)	1-5
Number of pages	5
Journal	Journal of Electroanalytical Chemistry
Volume	537
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-0728(02)01263-9
Publication status	Published - 29 Nov 2002

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AB - A modular semianalytic procedure, alternative to simulation, is described for predicting the transient current response to any applied potential signal under a wide variety of voltammetric conditions. Diverse geometries may be treated; the electrode reaction may have any degree of reversibility; homogeneous chemical reactions may be involved. Conceptually, the method consists of splitting the overall problem into three components, each of which is solved separately. Examples presented include cyclic voltammetry and (Osteryoung) square-wave voltammetry.

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KW - Voltammetry

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A fresh approach to voltammetric modelling

Abstract

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