Abstract
The reaction [W(CSe)(CO)2(Tp*)]NEt4 (Tp* = hydrotris(dimethylpyrazolyl)borate) with N-methyl-N-nitroso-4-toluenesulfonamide affords the nitrosyl complex [W(CSe)(CO)(NO)(Tp*)] which on treatment with excess [Re(THF)(CO)2(η-C5H5)] affords the cumuenic μ-carbido complex [WRe(μ-C)(CO)3(NO)(Tp*)(η-C5H5)] in addition to the μ-selenido complex [Re2(μ-Se)(CO)4(η-C5H5)2].
Original language | English |
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Pages (from-to) | 2356-2359 |
Journal | Chemical Communications |
Volume | 56 |
Issue number | 15 |
DOIs | |
Publication status | Published - 2020 |