A heterobimetallic cumulenic μ-carbido complex

Anthony F. Hill; Lachlan J. Watson

doi:10.1039/c9cc08172k

A heterobimetallic cumulenic μ-carbido complex

Anthony F. Hill^*, Lachlan J. Watson

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The reaction [W(CSe)(CO)₂(Tp∗)]NEt₄ (Tp∗ = hydrotris(dimethylpyrazolyl)borate) with N-methyl-N-nitroso-4-toluenesulfonamide affords the nitrosyl complex [W(CSe)(CO)(NO)(Tp∗)] which on treatment with excess [Re(THF)(CO)₂(η-C₅H₅)] affords the cumuenic μ-carbido complex [WRe(μ-C)(CO)₃(NO)(Tp∗)(η-C₅H₅)] in addition to the μ-selenido complex [Re₂(μ-Se)(CO)₄(η-C₅H₅)₂].

Original language	English
Pages (from-to)	2356-2359
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	15
DOIs	https://doi.org/10.1039/c9cc08172k
Publication status	Published - 21 Feb 2020

Access to Document

10.1039/c9cc08172k

Cite this

@article{bce9d0638dcd467ebe053d353b7c7d8e,

title = "A heterobimetallic cumulenic μ-carbido complex",

abstract = "The reaction [W(CSe)(CO)2(Tp∗)]NEt4 (Tp∗ = hydrotris(dimethylpyrazolyl)borate) with N-methyl-N-nitroso-4-toluenesulfonamide affords the nitrosyl complex [W(CSe)(CO)(NO)(Tp∗)] which on treatment with excess [Re(THF)(CO)2(η-C5H5)] affords the cumuenic μ-carbido complex [WRe(μ-C)(CO)3(NO)(Tp∗)(η-C5H5)] in addition to the μ-selenido complex [Re2(μ-Se)(CO)4(η-C5H5)2].",

author = "Hill, {Anthony F.} and Watson, {Lachlan J.}",

note = "Publisher Copyright: {\textcopyright} 2020 The Royal Society of Chemistry.",

year = "2020",

month = feb,

day = "21",

doi = "10.1039/c9cc08172k",

language = "English",

volume = "56",

pages = "2356--2359",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "15",

}

TY - JOUR

T1 - A heterobimetallic cumulenic μ-carbido complex

AU - Hill, Anthony F.

AU - Watson, Lachlan J.

PY - 2020/2/21

Y1 - 2020/2/21

N2 - The reaction [W(CSe)(CO)2(Tp∗)]NEt4 (Tp∗ = hydrotris(dimethylpyrazolyl)borate) with N-methyl-N-nitroso-4-toluenesulfonamide affords the nitrosyl complex [W(CSe)(CO)(NO)(Tp∗)] which on treatment with excess [Re(THF)(CO)2(η-C5H5)] affords the cumuenic μ-carbido complex [WRe(μ-C)(CO)3(NO)(Tp∗)(η-C5H5)] in addition to the μ-selenido complex [Re2(μ-Se)(CO)4(η-C5H5)2].

AB - The reaction [W(CSe)(CO)2(Tp∗)]NEt4 (Tp∗ = hydrotris(dimethylpyrazolyl)borate) with N-methyl-N-nitroso-4-toluenesulfonamide affords the nitrosyl complex [W(CSe)(CO)(NO)(Tp∗)] which on treatment with excess [Re(THF)(CO)2(η-C5H5)] affords the cumuenic μ-carbido complex [WRe(μ-C)(CO)3(NO)(Tp∗)(η-C5H5)] in addition to the μ-selenido complex [Re2(μ-Se)(CO)4(η-C5H5)2].

UR - http://www.scopus.com/inward/record.url?scp=85080846364&partnerID=8YFLogxK

U2 - 10.1039/c9cc08172k

DO - 10.1039/c9cc08172k

M3 - Article

SN - 1359-7345

VL - 56

SP - 2356

EP - 2359

JO - Chemical Communications

JF - Chemical Communications

IS - 15

ER -

A heterobimetallic cumulenic μ-carbido complex

Abstract

Access to Document

Other files and links

Fingerprint

Cite this