A homoleptic hydrotris(methimazolyl)borate complex of titanium

Anthony F. Hill; Matthew K. Smith

doi:10.1039/b707265a

A homoleptic hydrotris(methimazolyl)borate complex of titanium

Anthony F. Hill^*, Matthew K. Smith

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The reaction of [Ti₂(-Cl)₂(thf)₂(η- C₈H₈)₂] with Na[HB(mt)₃] (mt = methimazolyl) provides the unusual salt [Ti{HB(mt)₃} ₂][TiCl₄(thf)₂], the cation of which features homoleptic Ti^IIIS₆ coordination.

Original language	English
Pages (from-to)	3363-3364
Number of pages	2
Journal	Dalton Transactions
Issue number	31
DOIs	https://doi.org/10.1039/b707265a
Publication status	Published - 2007

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@article{4192b9641e3747308d482b4a665adc05,

title = "A homoleptic hydrotris(methimazolyl)borate complex of titanium",

abstract = "The reaction of [Ti2(-Cl)2(thf)2(η- C8H8)2] with Na[HB(mt)3] (mt = methimazolyl) provides the unusual salt [Ti{HB(mt)3} 2][TiCl4(thf)2], the cation of which features homoleptic TiIIIS6 coordination.",

author = "Hill, {Anthony F.} and Smith, {Matthew K.}",

year = "2007",

doi = "10.1039/b707265a",

language = "English",

pages = "3363--3364",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

number = "31",

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T1 - A homoleptic hydrotris(methimazolyl)borate complex of titanium

AU - Hill, Anthony F.

AU - Smith, Matthew K.

PY - 2007

Y1 - 2007

N2 - The reaction of [Ti2(-Cl)2(thf)2(η- C8H8)2] with Na[HB(mt)3] (mt = methimazolyl) provides the unusual salt [Ti{HB(mt)3} 2][TiCl4(thf)2], the cation of which features homoleptic TiIIIS6 coordination.

AB - The reaction of [Ti2(-Cl)2(thf)2(η- C8H8)2] with Na[HB(mt)3] (mt = methimazolyl) provides the unusual salt [Ti{HB(mt)3} 2][TiCl4(thf)2], the cation of which features homoleptic TiIIIS6 coordination.

UR - http://www.scopus.com/inward/record.url?scp=34547568136&partnerID=8YFLogxK

U2 - 10.1039/b707265a

DO - 10.1039/b707265a

M3 - Article

SN - 1477-9226

SP - 3363

EP - 3364

JO - Dalton Transactions

JF - Dalton Transactions

IS - 31

ER -

A homoleptic hydrotris(methimazolyl)borate complex of titanium

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