A hybrid ruthenium alkynyl/zinc porphyrin "Cross Fourchée" with large cubic NLO properties

Areej Merhi, Guillaume Grelaud, Katy A. Green, Ngo Hoang Minh, Michael Reynolds, Isabelle Ledoux*, Adam Barlow, Genmiao Wang, Marie P. Cifuentes, Mark G. Humphrey, Frédéric Paul, Christine O. Paul-Roth

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    7 Citations (Scopus)

    Abstract

    A new Zn(II) porphyrin-cored ruthenium alkynyl dendrimer (2) containing twelve Ru(κ2-dppe)2 bis-alkynyl fragments has been prepared in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(II) and shown to be highly active for third-harmonic generation (THG) at 1907 nm.

    Original languageEnglish
    Pages (from-to)7748-7751
    Number of pages4
    JournalDalton Transactions
    Volume44
    Issue number17
    DOIs
    Publication statusPublished - 7 May 2015

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