A hybrid ruthenium alkynyl/zinc porphyrin "Cross Fourchée" with large cubic NLO properties

Areej Merhi; Guillaume Grelaud; Katy A. Green; Ngo Hoang Minh; Michael Reynolds; Isabelle Ledoux; Adam Barlow; Genmiao Wang; Marie P. Cifuentes; Mark G. Humphrey; Frédéric Paul; Christine O. Paul-Roth

doi:10.1039/c5dt00768b

A hybrid ruthenium alkynyl/zinc porphyrin "Cross Fourchée" with large cubic NLO properties

Areej Merhi
, Guillaume Grelaud
, Katy A. Green
, Ngo Hoang Minh
, Michael Reynolds
, Isabelle Ledoux^*
, Adam Barlow
, Genmiao Wang
, Marie P. Cifuentes
, Mark G. Humphrey
, Frédéric Paul
, Christine O. Paul-Roth

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A new Zn(II) porphyrin-cored ruthenium alkynyl dendrimer (2) containing twelve Ru(κ²-dppe)₂ bis-alkynyl fragments has been prepared in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(II) and shown to be highly active for third-harmonic generation (THG) at 1907 nm.

Original language	English
Pages (from-to)	7748-7751
Number of pages	4
Journal	Dalton Transactions
Volume	44
Issue number	17
DOIs	https://doi.org/10.1039/c5dt00768b
Publication status	Published - 7 May 2015

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10.1039/c5dt00768b

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title = "A hybrid ruthenium alkynyl/zinc porphyrin {"}Cross Fourch{\'e}e{"} with large cubic NLO properties",

abstract = "A new Zn(II) porphyrin-cored ruthenium alkynyl dendrimer (2) containing twelve Ru(κ2-dppe)2 bis-alkynyl fragments has been prepared in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(II) and shown to be highly active for third-harmonic generation (THG) at 1907 nm.",

author = "Areej Merhi and Guillaume Grelaud and Green, \{Katy A.\} and Minh, \{Ngo Hoang\} and Michael Reynolds and Isabelle Ledoux and Adam Barlow and Genmiao Wang and Cifuentes, \{Marie P.\} and Humphrey, \{Mark G.\} and Fr{\'e}d{\'e}ric Paul and Paul-Roth, \{Christine O.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

month = may,

day = "7",

doi = "10.1039/c5dt00768b",

language = "English",

volume = "44",

pages = "7748--7751",

journal = "Dalton Transactions",

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T1 - A hybrid ruthenium alkynyl/zinc porphyrin "Cross Fourchée" with large cubic NLO properties

AU - Merhi, Areej

AU - Grelaud, Guillaume

AU - Green, Katy A.

AU - Minh, Ngo Hoang

AU - Reynolds, Michael

AU - Ledoux, Isabelle

AU - Barlow, Adam

AU - Wang, Genmiao

AU - Cifuentes, Marie P.

AU - Humphrey, Mark G.

AU - Paul, Frédéric

AU - Paul-Roth, Christine O.

PY - 2015/5/7

Y1 - 2015/5/7

N2 - A new Zn(II) porphyrin-cored ruthenium alkynyl dendrimer (2) containing twelve Ru(κ2-dppe)2 bis-alkynyl fragments has been prepared in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(II) and shown to be highly active for third-harmonic generation (THG) at 1907 nm.

AB - A new Zn(II) porphyrin-cored ruthenium alkynyl dendrimer (2) containing twelve Ru(κ2-dppe)2 bis-alkynyl fragments has been prepared in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(II) and shown to be highly active for third-harmonic generation (THG) at 1907 nm.

UR - https://www.scopus.com/pages/publications/84928743097

U2 - 10.1039/c5dt00768b

DO - 10.1039/c5dt00768b

M3 - Article

SN - 1477-9226

VL - 44

SP - 7748

EP - 7751

JO - Dalton Transactions

JF - Dalton Transactions

IS - 17

ER -

A hybrid ruthenium alkynyl/zinc porphyrin "Cross Fourchée" with large cubic NLO properties

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