A mercury bis(tricarbido) complex: [Hg{C≡C-C≡W(CO) 2Tp}2-(dmso)4](dmso)2 (Tp = hydrotrispyrazolylborate)

Rian D. Dewhurst; Anthony F. Hill; Anthony C. Willis

doi:10.1039/b412972e

A mercury bis(tricarbido) complex: [Hg{C≡C-C≡W(CO) ₂Tp}₂-(dmso)₄](dmso)₂ (Tp = hydrotrispyrazolylborate)

Rian D. Dewhurst, Anthony F. Hill^*, Anthony C. Willis

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Fluoride mediated desilylation of the propargylidyne complex [W(≡C-C≡CSiMe₃)(CO)₂{HB(pz)₃)] (pz = pyrazol-1-yl) in the presence of mercury(II) chloride provides the novel bis(tricarbido)complex [Hg{C≡C-C≡W(CO)₂(HB(pz)3}} ₂], which was structurally characterised as a dmso hexasolvate.

Original language	English
Pages (from-to)	2826-2827
Number of pages	2
Journal	Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/b412972e
Publication status	Published - 21 Dec 2004

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abstract = "Fluoride mediated desilylation of the propargylidyne complex [W(≡C-C≡CSiMe3)(CO)2{HB(pz)3)] (pz = pyrazol-1-yl) in the presence of mercury(II) chloride provides the novel bis(tricarbido)complex [Hg{C≡C-C≡W(CO)2(HB(pz)3}} 2], which was structurally characterised as a dmso hexasolvate.",

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AU - Hill, Anthony F.

AU - Willis, Anthony C.

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AB - Fluoride mediated desilylation of the propargylidyne complex [W(≡C-C≡CSiMe3)(CO)2{HB(pz)3)] (pz = pyrazol-1-yl) in the presence of mercury(II) chloride provides the novel bis(tricarbido)complex [Hg{C≡C-C≡W(CO)2(HB(pz)3}} 2], which was structurally characterised as a dmso hexasolvate.

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A mercury bis(tricarbido) complex: [Hg{C≡C-C≡W(CO) ₂Tp}₂-(dmso)₄](dmso)₂ (Tp = hydrotrispyrazolylborate)

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