A metallacyclic λ5-phosphaalkenyl complex of ruthenium(II): X-ray structure of [Ru {κ2-P(=O)CButC(=O)} (CNBut)2(PPh3)2]

AF Hill; AJP White; DJ Williams; JDET Wilton-Ely

doi:10.1039/a707987g

A metallacyclic λ⁵-phosphaalkenyl complex of ruthenium(II): X-ray structure of [Ru {κ²-P(=O)CBu^tC(=O)} (CNBu^t)₂(PPh₃)₂]

AF Hill, AJP White, DJ Williams, JDET Wilton-Ely

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The reaction of [Ru(P=CHBu^t)Cl(CO)(PPh₃)₂] 1 or [Ru(P=CHBu^t)Cl(CNBu^t)(CO)(PPh₃)₂] 2b with excess pivalo isonitrile under aerobic conditions provides the novel metallacyclic λ⁵-phosphaalkenyl-P complex [Ru{κ²-P(=O)CBu^tC(=O)}(CNBu^t) ₂(PPh₃)₂], which has been crystallographically characterised.

Original language	English
Pages (from-to)	367-368
Number of pages	2
Journal	Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/a707987g
Publication status	Published - 7 Feb 1998
Externally published	Yes

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title = "A metallacyclic λ5-phosphaalkenyl complex of ruthenium(II): X-ray structure of [Ru {κ2-P(=O)CButC(=O)} (CNBut)2(PPh3)2]",

abstract = "The reaction of [Ru(P=CHBut)Cl(CO)(PPh3)2] 1 or [Ru(P=CHBut)Cl(CNBut)(CO)(PPh3)2] 2b with excess pivalo isonitrile under aerobic conditions provides the novel metallacyclic λ5-phosphaalkenyl-P complex [Ru{κ2-P(=O)CButC(=O)}(CNBut) 2(PPh3)2], which has been crystallographically characterised.",

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author = "AF Hill and AJP White and DJ Williams and JDET Wilton-Ely",

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T2 - X-ray structure of [Ru {κ2-P(=O)CButC(=O)} (CNBut)2(PPh3)2]

AU - Hill, AF

AU - White, AJP

AU - Williams, DJ

AU - Wilton-Ely, JDET

PY - 1998/2/7

Y1 - 1998/2/7

N2 - The reaction of [Ru(P=CHBut)Cl(CO)(PPh3)2] 1 or [Ru(P=CHBut)Cl(CNBut)(CO)(PPh3)2] 2b with excess pivalo isonitrile under aerobic conditions provides the novel metallacyclic λ5-phosphaalkenyl-P complex [Ru{κ2-P(=O)CButC(=O)}(CNBut) 2(PPh3)2], which has been crystallographically characterised.

AB - The reaction of [Ru(P=CHBut)Cl(CO)(PPh3)2] 1 or [Ru(P=CHBut)Cl(CNBut)(CO)(PPh3)2] 2b with excess pivalo isonitrile under aerobic conditions provides the novel metallacyclic λ5-phosphaalkenyl-P complex [Ru{κ2-P(=O)CButC(=O)}(CNBut) 2(PPh3)2], which has been crystallographically characterised.

KW - Alkynes

KW - Bond

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DO - 10.1039/a707987g

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JF - Chemical Communications

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ER -

A metallacyclic λ⁵-phosphaalkenyl complex of ruthenium(II): X-ray structure of [Ru {κ²-P(=O)CBu^tC(=O)} (CNBu^t)₂(PPh₃)₂]

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