A non-equilibrium free energy theorem for deterministic systems

D. J. Evans*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    85 Citations (Scopus)

    Abstract

    Jarzynski and Crooks have recently shown that equilibrium free energy differences can be computed from non-equilibrium thermodynamic path integrals. In the present paper we give a new derivation of this extraordinary relation. Our derivation which is valid for time reversible deterministic systems highlights the close relationship between the non-equilibrium free energy theorems and the fluctuation theorem.

    Original languageEnglish
    Pages (from-to)1551-1554
    Number of pages4
    JournalMolecular Physics
    Volume101
    Issue number10
    DOIs
    Publication statusPublished - May 2003

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