A proof of Clausius' theorem for time reversible deterministic microscopic dynamics

Denis J. Evans, Stephen R. Williams, Debra J. Searles

    Research output: Contribution to journalArticlepeer-review

    18 Citations (Scopus)

    Abstract

    In 1854 Clausius proved the famous theorem that bears his name by assuming the second "law" of thermodynamics. In the present paper we give a proof that requires no such assumption. Our proof rests on the laws of mechanics, a T-mixing property, an ergodic consistency condition, and on the axiom of causality. Our result relies on some recently derived theorems, such as the Evans-Searles and the Crooks fluctuation theorems and the recently discovered relaxation and dissipation theorems.

    Original languageEnglish
    Article number204113
    JournalJournal of Chemical Physics
    Volume134
    Issue number20
    DOIs
    Publication statusPublished - 28 May 2011

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