A Rapid and Straightforward Supramolecular Self-Assembly Experiment to Prepare and Characterize a Triple Helicate Complex

Nicholas G. White

doi:10.1021/acs.jchemed.7b00674

A Rapid and Straightforward Supramolecular Self-Assembly Experiment to Prepare and Characterize a Triple Helicate Complex

Nicholas G. White^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

This experiment prepares a large (M_r: 1821 g mol^-1) triple helicate complex quickly in one pot from inexpensive starting materials. The protocol illustrates the power of self-assembly in a simple manner that is suitable for second-year general chemistry students using reversible imine bond and metal-ligand bond formation. Plastic molecular models and ¹H NMR spectroscopy are used to elucidate the structure of the self-assembled product.

Original language	English
Pages (from-to)	648-651
Number of pages	4
Journal	Journal of Chemical Education
Volume	95
Issue number	4
DOIs	https://doi.org/10.1021/acs.jchemed.7b00674
Publication status	Published - 10 Apr 2018

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title = "A Rapid and Straightforward Supramolecular Self-Assembly Experiment to Prepare and Characterize a Triple Helicate Complex",

abstract = "This experiment prepares a large (Mr: 1821 g mol-1) triple helicate complex quickly in one pot from inexpensive starting materials. The protocol illustrates the power of self-assembly in a simple manner that is suitable for second-year general chemistry students using reversible imine bond and metal-ligand bond formation. Plastic molecular models and 1H NMR spectroscopy are used to elucidate the structure of the self-assembled product.",

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AB - This experiment prepares a large (Mr: 1821 g mol-1) triple helicate complex quickly in one pot from inexpensive starting materials. The protocol illustrates the power of self-assembly in a simple manner that is suitable for second-year general chemistry students using reversible imine bond and metal-ligand bond formation. Plastic molecular models and 1H NMR spectroscopy are used to elucidate the structure of the self-assembled product.

KW - Hands-On Learning/Manipulatives,Coordination Compounds

KW - Inorganic Chemistry

KW - Laboratory Instruction

KW - Organic Chemistry

KW - Second-Year Undergraduate

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ER -

A Rapid and Straightforward Supramolecular Self-Assembly Experiment to Prepare and Characterize a Triple Helicate Complex

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