A surface study of the native oxide upon a compositionally complex alloy

Y. Qiu; S. Thomas; R. K. Gupta; T. Gengenbach; R. Jones; N. Birbilis

doi:10.5006/2967

A surface study of the native oxide upon a compositionally complex alloy

Y. Qiu, S. Thomas, R. K. Gupta, T. Gengenbach, R. Jones, N. Birbilis^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The native surface oxide upon a single phase low-density compositionally complex alloy (CCA), AlTiVCr, was studied herein-owing to its exceptionally high aqueous corrosion resistance. The nature of the native surface oxide/surface film was elaborated in the context of corrosion resistance, based on results from electrochemical testing, secondary ion mass spectroscopy, and x-ray photoelectron spectroscopy. Selective oxidation and unoxidized metal in the surface film were observed. Such features are comparatively unique and posited to be relevant to CCAs and high entropy alloys more generally.

Original language	English
Pages (from-to)	1312-1317
Number of pages	6
Journal	Corrosion
Volume	74
Issue number	12
DOIs	https://doi.org/10.5006/2967
Publication status	Published - Dec 2018

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title = "A surface study of the native oxide upon a compositionally complex alloy",

abstract = "The native surface oxide upon a single phase low-density compositionally complex alloy (CCA), AlTiVCr, was studied herein-owing to its exceptionally high aqueous corrosion resistance. The nature of the native surface oxide/surface film was elaborated in the context of corrosion resistance, based on results from electrochemical testing, secondary ion mass spectroscopy, and x-ray photoelectron spectroscopy. Selective oxidation and unoxidized metal in the surface film were observed. Such features are comparatively unique and posited to be relevant to CCAs and high entropy alloys more generally.",

keywords = "Corrosion, High entropy alloys, Oxide films, Secondary ion mass spectroscopy (SIMS), X-ray photoelectron spectroscopy (XPS)",

author = "Y. Qiu and S. Thomas and Gupta, {R. K.} and T. Gengenbach and R. Jones and N. Birbilis",

note = "Publisher Copyright: {\textcopyright} 2018 NACE International.",

year = "2018",

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AU - Qiu, Y.

AU - Thomas, S.

AU - Gupta, R. K.

AU - Gengenbach, T.

AU - Jones, R.

AU - Birbilis, N.

PY - 2018/12

Y1 - 2018/12

N2 - The native surface oxide upon a single phase low-density compositionally complex alloy (CCA), AlTiVCr, was studied herein-owing to its exceptionally high aqueous corrosion resistance. The nature of the native surface oxide/surface film was elaborated in the context of corrosion resistance, based on results from electrochemical testing, secondary ion mass spectroscopy, and x-ray photoelectron spectroscopy. Selective oxidation and unoxidized metal in the surface film were observed. Such features are comparatively unique and posited to be relevant to CCAs and high entropy alloys more generally.

AB - The native surface oxide upon a single phase low-density compositionally complex alloy (CCA), AlTiVCr, was studied herein-owing to its exceptionally high aqueous corrosion resistance. The nature of the native surface oxide/surface film was elaborated in the context of corrosion resistance, based on results from electrochemical testing, secondary ion mass spectroscopy, and x-ray photoelectron spectroscopy. Selective oxidation and unoxidized metal in the surface film were observed. Such features are comparatively unique and posited to be relevant to CCAs and high entropy alloys more generally.

KW - Corrosion

KW - High entropy alloys

KW - Oxide films

KW - Secondary ion mass spectroscopy (SIMS)

KW - X-ray photoelectron spectroscopy (XPS)

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JO - Corrosion

JF - Corrosion

IS - 12

ER -

A surface study of the native oxide upon a compositionally complex alloy

Abstract

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