A symmetry interaction approach to [M2L2]4+ metallocycles and their self-catenation

Dan Preston; Amanda R. Inglis; Anna L. Garden; Paul E. Kruger

doi:10.1039/c9cc07130j

A symmetry interaction approach to [M₂L₂]⁴⁺ metallocycles and their self-catenation

Dan Preston^*, Amanda R. Inglis, Anna L. Garden, Paul E. Kruger

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Dinuclear [M₂L₂]ⁿ⁺ (M = Pd²⁺ or Pt²⁺) metallo-rectangles have a rich history, particularly in molecular recognition, including self-catenation events. These structures are mostly generated via a ligand-directed approach with cis-capped M²⁺ corners. We report here a symmetry interaction approach using 3 : 1 complementary denticity, giving a new route to [M₂L₂]⁴⁺ rectangles and their self-catenation.

Original language	English
Pages (from-to)	13271-13274
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	88
DOIs	https://doi.org/10.1039/c9cc07130j
Publication status	Published - 2019
Externally published	Yes

Access to Document

10.1039/c9cc07130j

Cite this

@article{be7c01b5ddaf40818c5bd48ed7123479,

title = "A symmetry interaction approach to [M2L2]4+ metallocycles and their self-catenation",

abstract = "Dinuclear [M2L2]n+ (M = Pd2+ or Pt2+) metallo-rectangles have a rich history, particularly in molecular recognition, including self-catenation events. These structures are mostly generated via a ligand-directed approach with cis-capped M2+ corners. We report here a symmetry interaction approach using 3 : 1 complementary denticity, giving a new route to [M2L2]4+ rectangles and their self-catenation.",

author = "Dan Preston and Inglis, {Amanda R.} and Garden, {Anna L.} and Kruger, {Paul E.}",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9cc07130j",

language = "English",

volume = "55",

pages = "13271--13274",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "88",

}

TY - JOUR

T1 - A symmetry interaction approach to [M2L2]4+ metallocycles and their self-catenation

AU - Preston, Dan

AU - Inglis, Amanda R.

AU - Garden, Anna L.

AU - Kruger, Paul E.

PY - 2019

Y1 - 2019

N2 - Dinuclear [M2L2]n+ (M = Pd2+ or Pt2+) metallo-rectangles have a rich history, particularly in molecular recognition, including self-catenation events. These structures are mostly generated via a ligand-directed approach with cis-capped M2+ corners. We report here a symmetry interaction approach using 3 : 1 complementary denticity, giving a new route to [M2L2]4+ rectangles and their self-catenation.

AB - Dinuclear [M2L2]n+ (M = Pd2+ or Pt2+) metallo-rectangles have a rich history, particularly in molecular recognition, including self-catenation events. These structures are mostly generated via a ligand-directed approach with cis-capped M2+ corners. We report here a symmetry interaction approach using 3 : 1 complementary denticity, giving a new route to [M2L2]4+ rectangles and their self-catenation.

UR - http://www.scopus.com/inward/record.url?scp=85074309887&partnerID=8YFLogxK

U2 - 10.1039/c9cc07130j

DO - 10.1039/c9cc07130j

M3 - Article

SN - 1359-7345

VL - 55

SP - 13271

EP - 13274

JO - Chemical Communications

JF - Chemical Communications

IS - 88

ER -

A symmetry interaction approach to [M₂L₂]⁴⁺ metallocycles and their self-catenation

Abstract

Access to Document

Other files and links

Fingerprint

Cite this