A symmetry interaction approach to [M2L2]4+ metallocycles and their self-catenation

Dan Preston; Amanda R. Inglis; Anna L. Garden; Paul E. Kruger

doi:10.1039/c9cc07130j

A symmetry interaction approach to [M₂L₂]⁴⁺ metallocycles and their self-catenation

Dan Preston^*, Amanda R. Inglis, Anna L. Garden, Paul E. Kruger

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Dinuclear [M₂L₂]ⁿ⁺ (M = Pd²⁺ or Pt²⁺) metallo-rectangles have a rich history, particularly in molecular recognition, including self-catenation events. These structures are mostly generated via a ligand-directed approach with cis-capped M²⁺ corners. We report here a symmetry interaction approach using 3 : 1 complementary denticity, giving a new route to [M₂L₂]⁴⁺ rectangles and their self-catenation.

Original language	English
Pages (from-to)	13271-13274
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	88
DOIs	https://doi.org/10.1039/c9cc07130j
Publication status	Published - 2019
Externally published	Yes

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abstract = "Dinuclear [M2L2]n+ (M = Pd2+ or Pt2+) metallo-rectangles have a rich history, particularly in molecular recognition, including self-catenation events. These structures are mostly generated via a ligand-directed approach with cis-capped M2+ corners. We report here a symmetry interaction approach using 3 : 1 complementary denticity, giving a new route to [M2L2]4+ rectangles and their self-catenation.",

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AU - Garden, Anna L.

AU - Kruger, Paul E.

PY - 2019

Y1 - 2019

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AB - Dinuclear [M2L2]n+ (M = Pd2+ or Pt2+) metallo-rectangles have a rich history, particularly in molecular recognition, including self-catenation events. These structures are mostly generated via a ligand-directed approach with cis-capped M2+ corners. We report here a symmetry interaction approach using 3 : 1 complementary denticity, giving a new route to [M2L2]4+ rectangles and their self-catenation.

UR - https://www.scopus.com/pages/publications/85074309887

U2 - 10.1039/c9cc07130j

DO - 10.1039/c9cc07130j

M3 - Article

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EP - 13274

JO - Chemical Communications

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IS - 88

ER -

A symmetry interaction approach to [M₂L₂]⁴⁺ metallocycles and their self-catenation

Abstract

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