A Thioketene Complex of Molybdenum(IV): Crystal Structure of [Mo{η 2-κ(C,S),σ-κ(S′)-S=C=CRC(=O)S}(=O){HB(pz) 3}] (R = C6H4Me-4, pz = Pyrazol-1-yl)

Anthony F. Hill; John M. Malget; Andrew J.P. White; David J. Williams

doi:10.1021/ic970712z

A Thioketene Complex of Molybdenum(IV): Crystal Structure of [Mo{η ²-κ(C,S),σ-κ(S′)-S=C=CRC(=O)S}(=O){HB(pz) ₃}] (R = C₆H₄Me-4, pz = Pyrazol-1-yl)

Anthony F. Hill^*
, John M. Malget
, Andrew J.P. White
, David J. Williams

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The reactions of two alkylidynemolybdenum complexes with carbon disulfide have been investigated and found to provide an unusual and structurally characterized metallacyclic thioketene complex [Mo-{eta(2)-kappa(C,S),sigma-kappa(S')-S=C=CRC(=O)S}(=O){HB-(pz)(3)}], leading to a reinterpretation of previous alkylidyne/CS2 coupling processes.

Original language	English
Pages (from-to)	598-600
Number of pages	3
Journal	Inorganic Chemistry
Volume	37
Issue number	3
DOIs	https://doi.org/10.1021/ic970712z
Publication status	Published - 9 Feb 1998
Externally published	Yes

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@article{41a343e9a8b747fa84437aef5a042521,

title = "A Thioketene Complex of Molybdenum(IV): Crystal Structure of [Mo\{η 2-κ(C,S),σ-κ(S′)-S=C=CRC(=O)S\}(=O)\{HB(pz) 3\}] (R = C6H4Me-4, pz = Pyrazol-1-yl)",

abstract = "The reactions of two alkylidynemolybdenum complexes with carbon disulfide have been investigated and found to provide an unusual and structurally characterized metallacyclic thioketene complex [Mo-\{eta(2)-kappa(C,S),sigma-kappa(S')-S=C=CRC(=O)S\}(=O)\{HB-(pz)(3)\}], leading to a reinterpretation of previous alkylidyne/CS2 coupling processes.",

keywords = "Alkylidyne, Metathesis, Carbonyl, Ligands",

author = "Hill, \{Anthony F.\} and Malget, \{John M.\} and White, \{Andrew J.P.\} and Williams, \{David J.\}",

note = "{\textcopyright} 1998 The Author(s)",

year = "1998",

month = feb,

day = "9",

doi = "10.1021/ic970712z",

language = "English",

volume = "37",

pages = "598--600",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "3",

}

TY - JOUR

T1 - A Thioketene Complex of Molybdenum(IV)

T2 - Crystal Structure of [Mo{η 2-κ(C,S),σ-κ(S′)-S=C=CRC(=O)S}(=O){HB(pz) 3}] (R = C6H4Me-4, pz = Pyrazol-1-yl)

AU - Hill, Anthony F.

AU - Malget, John M.

AU - White, Andrew J.P.

AU - Williams, David J.

PY - 1998/2/9

Y1 - 1998/2/9

N2 - The reactions of two alkylidynemolybdenum complexes with carbon disulfide have been investigated and found to provide an unusual and structurally characterized metallacyclic thioketene complex [Mo-{eta(2)-kappa(C,S),sigma-kappa(S')-S=C=CRC(=O)S}(=O){HB-(pz)(3)}], leading to a reinterpretation of previous alkylidyne/CS2 coupling processes.

AB - The reactions of two alkylidynemolybdenum complexes with carbon disulfide have been investigated and found to provide an unusual and structurally characterized metallacyclic thioketene complex [Mo-{eta(2)-kappa(C,S),sigma-kappa(S')-S=C=CRC(=O)S}(=O){HB-(pz)(3)}], leading to a reinterpretation of previous alkylidyne/CS2 coupling processes.

KW - Alkylidyne

KW - Metathesis

KW - Carbonyl

KW - Ligands

UR - https://www.scopus.com/pages/publications/0000393493

UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:000072037500032&DestLinkType=FullRecord&DestApp=WOS_CPL

U2 - 10.1021/ic970712z

DO - 10.1021/ic970712z

M3 - Article

C2 - 11670313

SN - 0020-1669

VL - 37

SP - 598

EP - 600

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 3

ER -

A Thioketene Complex of Molybdenum(IV): Crystal Structure of [Mo{η ²-κ(C,S),σ-κ(S′)-S=C=CRC(=O)S}(=O){HB(pz) ₃}] (R = C₆H₄Me-4, pz = Pyrazol-1-yl)

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