A three dimensional hydrogen bonded organic framework assembled through antielectrostatic hydrogen bonds

Duncan A. Cullen; Michael G. Gardiner; Nicholas G. White

doi:10.1039/c9cc06707h

A three dimensional hydrogen bonded organic framework assembled through antielectrostatic hydrogen bonds

Duncan A. Cullen, Michael G. Gardiner, Nicholas G. White^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

A crystalline 3D hydrogen bonded framework is assembled in water from tetrahedral tetraamidinium cations and antielectrostatically hydrogen bonded bicarbonate dimers. The framework forms in water, and represents a clear demonstration of the potency of these anti-Coulombic hydrogen bonds. Gentle heating of the framework (50 °C) releases CO₂ and water to give the neutral tetraamidine compound.

Original language	English
Pages (from-to)	12020-12023
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	80
DOIs	https://doi.org/10.1039/c9cc06707h
Publication status	Published - 2019

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title = "A three dimensional hydrogen bonded organic framework assembled through antielectrostatic hydrogen bonds",

abstract = "A crystalline 3D hydrogen bonded framework is assembled in water from tetrahedral tetraamidinium cations and antielectrostatically hydrogen bonded bicarbonate dimers. The framework forms in water, and represents a clear demonstration of the potency of these anti-Coulombic hydrogen bonds. Gentle heating of the framework (50 °C) releases CO2 and water to give the neutral tetraamidine compound.",

author = "Cullen, \{Duncan A.\} and Gardiner, \{Michael G.\} and White, \{Nicholas G.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2019.",

year = "2019",

doi = "10.1039/c9cc06707h",

language = "English",

volume = "55",

pages = "12020--12023",

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issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - A three dimensional hydrogen bonded organic framework assembled through antielectrostatic hydrogen bonds

AU - Cullen, Duncan A.

AU - Gardiner, Michael G.

AU - White, Nicholas G.

N1 - Publisher Copyright: © The Royal Society of Chemistry 2019.

PY - 2019

Y1 - 2019

N2 - A crystalline 3D hydrogen bonded framework is assembled in water from tetrahedral tetraamidinium cations and antielectrostatically hydrogen bonded bicarbonate dimers. The framework forms in water, and represents a clear demonstration of the potency of these anti-Coulombic hydrogen bonds. Gentle heating of the framework (50 °C) releases CO2 and water to give the neutral tetraamidine compound.

AB - A crystalline 3D hydrogen bonded framework is assembled in water from tetrahedral tetraamidinium cations and antielectrostatically hydrogen bonded bicarbonate dimers. The framework forms in water, and represents a clear demonstration of the potency of these anti-Coulombic hydrogen bonds. Gentle heating of the framework (50 °C) releases CO2 and water to give the neutral tetraamidine compound.

UR - https://www.scopus.com/pages/publications/85072903668

U2 - 10.1039/c9cc06707h

DO - 10.1039/c9cc06707h

M3 - Article

SN - 1359-7345

VL - 55

SP - 12020

EP - 12023

JO - Chemical Communications

JF - Chemical Communications

IS - 80

ER -

A three dimensional hydrogen bonded organic framework assembled through antielectrostatic hydrogen bonds

Abstract

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