A transition-metal-free fast track to flavones and 3-arylcoumarins

Mostafa Golshani; Mehdi Khoobi; Nafiseh Jalalimanesh; Farnaz Jafarpour; Alireza Ariafard

doi:10.1039/c7cc02107k

A transition-metal-free fast track to flavones and 3-arylcoumarins

Mostafa Golshani, Mehdi Khoobi^*, Nafiseh Jalalimanesh, Farnaz Jafarpour, Alireza Ariafard

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

A highly regioselective and transition-metal free one-pot arylation of chromenones with arylboronic acids has been achieved employing K₂S₂O₈. The procedure consists of a sequence of some reactions including an arylation/decarboxylation cascade and proceeds well in aqueous media to afford biologically interesting flavones and 3-arylcoumarins. This method exhibited excellent selectivity and functional group tolerance under mild conditions. The reaction also showed perfect efficacy for the preparation of styryl coumarins.

Original language	English
Pages (from-to)	10676-10679
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	77
DOIs	https://doi.org/10.1039/c7cc02107k
Publication status	Published - 2017
Externally published	Yes

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title = "A transition-metal-free fast track to flavones and 3-arylcoumarins",

abstract = "A highly regioselective and transition-metal free one-pot arylation of chromenones with arylboronic acids has been achieved employing K2S2O8. The procedure consists of a sequence of some reactions including an arylation/decarboxylation cascade and proceeds well in aqueous media to afford biologically interesting flavones and 3-arylcoumarins. This method exhibited excellent selectivity and functional group tolerance under mild conditions. The reaction also showed perfect efficacy for the preparation of styryl coumarins.",

author = "Mostafa Golshani and Mehdi Khoobi and Nafiseh Jalalimanesh and Farnaz Jafarpour and Alireza Ariafard",

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year = "2017",

doi = "10.1039/c7cc02107k",

language = "English",

volume = "53",

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publisher = "Royal Society of Chemistry",

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T1 - A transition-metal-free fast track to flavones and 3-arylcoumarins

AU - Golshani, Mostafa

AU - Khoobi, Mehdi

AU - Jalalimanesh, Nafiseh

AU - Jafarpour, Farnaz

AU - Ariafard, Alireza

PY - 2017

Y1 - 2017

N2 - A highly regioselective and transition-metal free one-pot arylation of chromenones with arylboronic acids has been achieved employing K2S2O8. The procedure consists of a sequence of some reactions including an arylation/decarboxylation cascade and proceeds well in aqueous media to afford biologically interesting flavones and 3-arylcoumarins. This method exhibited excellent selectivity and functional group tolerance under mild conditions. The reaction also showed perfect efficacy for the preparation of styryl coumarins.

AB - A highly regioselective and transition-metal free one-pot arylation of chromenones with arylboronic acids has been achieved employing K2S2O8. The procedure consists of a sequence of some reactions including an arylation/decarboxylation cascade and proceeds well in aqueous media to afford biologically interesting flavones and 3-arylcoumarins. This method exhibited excellent selectivity and functional group tolerance under mild conditions. The reaction also showed perfect efficacy for the preparation of styryl coumarins.

UR - https://www.scopus.com/pages/publications/85030241941

U2 - 10.1039/c7cc02107k

DO - 10.1039/c7cc02107k

M3 - Article

C2 - 28905058

AN - SCOPUS:85030241941

SN - 1359-7345

VL - 53

SP - 10676

EP - 10679

JO - Chemical Communications

JF - Chemical Communications

IS - 77

ER -

A transition-metal-free fast track to flavones and 3-arylcoumarins

Abstract

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