Alkylidene–Dithiocarbamate coupling—crystal structure of [Ru{κ2-CH(C6H4OMe-4)SC(NC4H8)S}{κ2-S2CNC4H8}(CO)(PPh3)]

Darren J. Cook; Karsten J. Harlow; Anthony F. Hill; Tom Welton; Andrew J.P.  White; David J. Williams

doi:10.1039/a801542b

Alkylidene–Dithiocarbamate coupling—crystal structure of [Ru{κ2-CH(C6H4OMe-4)SC(NC4H8)S}{κ2-S2CNC4H8}(CO)(PPh3)]

Darren J. Cook, Karsten J. Harlow, Anthony F. Hill, Tom Welton, Andrew J.P. White, David J. Williams

Research output: Contribution to journal › Letter › peer-review

9 Citations (Scopus)

Abstract

The reaction of [Ru(=CC6H4OMe-4)Cl(CO)(PPh3)(2)] with [NH4][S2CNC4H8] provides the structurally characterised metallacycle [Ru{kappa(2)-CH(C6H4OMe-4)SC(NC4H8)S}(S2CNC4H8)(CO)(PPh3)], related examples of which arise from the reactions of xanthate or dithiocarbamate salts with the alkylidene compounds [MCl2(=CHR)(CO)(PPh3)(2)](M = Ru or Os; R = Ph or C6H4OMe-4) and [OsCl(=CHR)(OH2)(CO)(PPh3)(2)]ClO4.

Original language	English
Pages (from-to)	311-314
Number of pages	3
Journal	New Journal of Chemistry
Volume	22
Issue number	4
DOIs	https://doi.org/10.1039/a801542b
Publication status	Published - Mar 1998
Externally published	Yes

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@article{c338643b84024b13b520d1d870a86e6c,

title = "Alkylidene–Dithiocarbamate coupling—crystal structure of [Ru{κ2-CH(C6H4OMe-4)SC(NC4H8)S}{κ2-S2CNC4H8}(CO)(PPh3)]",

abstract = "The reaction of [Ru(=CC6H4OMe-4)Cl(CO)(PPh3)(2)] with [NH4][S2CNC4H8] provides the structurally characterised metallacycle [Ru{kappa(2)-CH(C6H4OMe-4)SC(NC4H8)S}(S2CNC4H8)(CO)(PPh3)], related examples of which arise from the reactions of xanthate or dithiocarbamate salts with the alkylidene compounds [MCl2(=CHR)(CO)(PPh3)(2)](M = Ru or Os; R = Ph or C6H4OMe-4) and [OsCl(=CHR)(OH2)(CO)(PPh3)(2)]ClO4.",

keywords = "Complexes, Ruthenium(ii), Methylene, Carbonyl",

author = "Cook, {Darren J.} and Harlow, {Karsten J.} and Hill, {Anthony F.} and Tom Welton and White, {Andrew J.P.} and Williams, {David J.}",

year = "1998",

month = mar,

doi = "10.1039/a801542b",

language = "English",

volume = "22",

pages = "311--314",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

number = "4",

}

TY - JOUR

T1 - Alkylidene–Dithiocarbamate coupling—crystal structure of [Ru{κ2-CH(C6H4OMe-4)SC(NC4H8)S}{κ2-S2CNC4H8}(CO)(PPh3)]

AU - Cook, Darren J.

AU - Harlow, Karsten J.

AU - Hill, Anthony F.

AU - Welton, Tom

AU - White, Andrew J.P.

AU - Williams, David J.

PY - 1998/3

Y1 - 1998/3

N2 - The reaction of [Ru(=CC6H4OMe-4)Cl(CO)(PPh3)(2)] with [NH4][S2CNC4H8] provides the structurally characterised metallacycle [Ru{kappa(2)-CH(C6H4OMe-4)SC(NC4H8)S}(S2CNC4H8)(CO)(PPh3)], related examples of which arise from the reactions of xanthate or dithiocarbamate salts with the alkylidene compounds [MCl2(=CHR)(CO)(PPh3)(2)](M = Ru or Os; R = Ph or C6H4OMe-4) and [OsCl(=CHR)(OH2)(CO)(PPh3)(2)]ClO4.

AB - The reaction of [Ru(=CC6H4OMe-4)Cl(CO)(PPh3)(2)] with [NH4][S2CNC4H8] provides the structurally characterised metallacycle [Ru{kappa(2)-CH(C6H4OMe-4)SC(NC4H8)S}(S2CNC4H8)(CO)(PPh3)], related examples of which arise from the reactions of xanthate or dithiocarbamate salts with the alkylidene compounds [MCl2(=CHR)(CO)(PPh3)(2)](M = Ru or Os; R = Ph or C6H4OMe-4) and [OsCl(=CHR)(OH2)(CO)(PPh3)(2)]ClO4.

KW - Complexes

KW - Ruthenium(ii)

KW - Methylene

KW - Carbonyl

UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:000073569700002&DestLinkType=FullRecord&DestApp=WOS_CPL

U2 - 10.1039/a801542b

DO - 10.1039/a801542b

M3 - Letter

SN - 1144-0546

VL - 22

SP - 311

EP - 314

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 4

ER -

Alkylidene–Dithiocarbamate coupling—crystal structure of [Ru{κ2-CH(C6H4OMe-4)SC(NC4H8)S}{κ2-S2CNC4H8}(CO)(PPh3)]

Abstract

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