An enantioselective synthesis of the epoxyquinol (+)-isoepiepoformin

Lorenzo V. White; Christine E. Dietinger; David M. Pinkerton; Anthony C. Willis; Martin G. Banwell

doi:10.1002/ejoc.201000642

An enantioselective synthesis of the epoxyquinol (+)-isoepiepoformin

Lorenzo V. White, Christine E. Dietinger, David M. Pinkerton, Anthony C. Willis, Martin G. Banwell

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The epoxyquinol natural product: (+)-isoepiepoformin (1) has been synthesized for the first time and in an unambiguous fashion by using the scalemic cis-l,2-dihydrocatechol 2 as starting material. The spectroscopic data derived from the synthetic sample of compound 1 match those reported in the literature for the natural product and thereby confirm the structure assigned to the latter.

Original language	English
Pages (from-to)	4365-4367
Number of pages	3
Journal	European Journal of Organic Chemistry
Issue number	23
DOIs	https://doi.org/10.1002/ejoc.201000642
Publication status	Published - Aug 2010

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abstract = "The epoxyquinol natural product: (+)-isoepiepoformin (1) has been synthesized for the first time and in an unambiguous fashion by using the scalemic cis-l,2-dihydrocatechol 2 as starting material. The spectroscopic data derived from the synthetic sample of compound 1 match those reported in the literature for the natural product and thereby confirm the structure assigned to the latter.",

keywords = "(+)-isoepiepoformin, 2-dihydrocatechol, C-C coupling, Cis-l, Enones, Natural products, Total synthesis",

author = "White, {Lorenzo V.} and Dietinger, {Christine E.} and Pinkerton, {David M.} and Willis, {Anthony C.} and Banwell, {Martin G.}",

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AU - Willis, Anthony C.

AU - Banwell, Martin G.

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KW - C-C coupling

KW - Cis-l

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KW - Total synthesis

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An enantioselective synthesis of the epoxyquinol (+)-isoepiepoformin

Abstract

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