An Organometallic Erbium Bismuth Cluster Complex Comprising a Bi $_6$ $^6–$ Zintl Ion

Florian Benner; Elizabeth R. Pugliese; Reece Q. Marsden; Richard J. Staples; Nicholas F. Chilton; Selvan Demir

doi:10.1021/acs.inorgchem.4c02636

An Organometallic Erbium Bismuth Cluster Complex Comprising a Bi $_6$ $^6–$ Zintl Ion

Florian Benner, Elizabeth R. Pugliese, Reece Q. Marsden, Richard J. Staples, Nicholas F. Chilton, Selvan Demir

Research School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

An organometallic erbium bismuth cluster complex,[K(THF)4]2[Cp*2Er2Bi6] (1), featuring a heterometallocubanecore was isolated. The cube emerges from the rare Bi66− Zintl ion,bridging two erbium centers for the first time. SQUID magneto-metry and ab initio calculations uncovered dominant antiferro-magnetic coupling enabled through the chair-like hexabismuthanion. The gained insight will promote the design of futurepolynuclear magnetic molecules comprising prolate lanthanideions

Original language	English
Pages (from-to)	20250-20256
Number of pages	7
Journal	Inorganic Chemistry
Volume	63
Issue number	43
DOIs	https://doi.org/10.1021/acs.inorgchem.4c02636
Publication status	Published - Oct 2024

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10.1021/acs.inorgchem.4c02636

https://pubs.acs.org/doi/10.1021/acs.inorgchem.4c02636

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title = "An Organometallic Erbium Bismuth Cluster Complex Comprising a Bi $_6$ $^6–$ Zintl Ion",

abstract = "An organometallic erbium bismuth cluster complex,[K(THF)4]2[Cp*2Er2Bi6] (1), featuring a heterometallocubanecore was isolated. The cube emerges from the rare Bi66− Zintl ion,bridging two erbium centers for the first time. SQUID magneto-metry and ab initio calculations uncovered dominant antiferro-magnetic coupling enabled through the chair-like hexabismuthanion. The gained insight will promote the design of futurepolynuclear magnetic molecules comprising prolate lanthanideions",

author = "Florian Benner and Pugliese, {Elizabeth R.} and Marsden, {Reece Q.} and Staples, {Richard J.} and Chilton, {Nicholas F.} and Selvan Demir",

year = "2024",

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doi = "10.1021/acs.inorgchem.4c02636",

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T1 - An Organometallic Erbium Bismuth Cluster Complex Comprising a Bi $_6$ $^6–$ Zintl Ion

AU - Benner, Florian

AU - Pugliese, Elizabeth R.

AU - Marsden, Reece Q.

AU - Staples, Richard J.

AU - Chilton, Nicholas F.

AU - Demir, Selvan

PY - 2024/10

Y1 - 2024/10

N2 - An organometallic erbium bismuth cluster complex,[K(THF)4]2[Cp*2Er2Bi6] (1), featuring a heterometallocubanecore was isolated. The cube emerges from the rare Bi66− Zintl ion,bridging two erbium centers for the first time. SQUID magneto-metry and ab initio calculations uncovered dominant antiferro-magnetic coupling enabled through the chair-like hexabismuthanion. The gained insight will promote the design of futurepolynuclear magnetic molecules comprising prolate lanthanideions

AB - An organometallic erbium bismuth cluster complex,[K(THF)4]2[Cp*2Er2Bi6] (1), featuring a heterometallocubanecore was isolated. The cube emerges from the rare Bi66− Zintl ion,bridging two erbium centers for the first time. SQUID magneto-metry and ab initio calculations uncovered dominant antiferro-magnetic coupling enabled through the chair-like hexabismuthanion. The gained insight will promote the design of futurepolynuclear magnetic molecules comprising prolate lanthanideions

U2 - 10.1021/acs.inorgchem.4c02636

DO - 10.1021/acs.inorgchem.4c02636

M3 - Article

SN - 0020-1669

VL - 63

SP - 20250

EP - 20256

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 43

ER -

An Organometallic Erbium Bismuth Cluster Complex Comprising a Bi $_6$ $^6–$ Zintl Ion

Abstract

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