An organometallic tetranuclear complex of μ4-PO4: [{(Cp*Cr)2(μ-OMe)2} 2(μ4-PO4)]X (X - I, PF6)

Richard Y.C. Shin; Geok Kheng Tan; Lip Lin Koh; Lai Yoong Goh; Richard D. Webster

doi:10.1021/om048974d

An organometallic tetranuclear complex of μ₄-PO₄: [{(C_p*Cr)₂(μ-OMe)₂} ₂(μ₄-PO₄)]X (X - I, PF₆)

Richard Y.C. Shin, Geok Kheng Tan, Lip Lin Koh, Lai Yoong Goh^*, Richard D. Webster

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The first discrete organometallic tetranuclear μ₄-PO ₄ complex, [{(Cp*Cr)₂(μ-OMe)₂} ₂(μ₄-PO₄)]⁺ (5; Cp* = η⁵-C₅Me₅), was isolated as the iodide and PF₆ salts from the reaction between NaH₂PO₄ and [Cp*Cr(μ-OMe)I]₂ (2), which was derived from thiolate methylation of [Cp*Cr{η³-HN(CH₂CH ₂S)₂}] (1) with MeI in MeOH.

Original language	English
Pages (from-to)	1401-1403
Number of pages	3
Journal	Organometallics
Volume	24
Issue number	7
DOIs	https://doi.org/10.1021/om048974d
Publication status	Published - 28 Mar 2005

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title = "An organometallic tetranuclear complex of μ4-PO4: [{(Cp*Cr)2(μ-OMe)2} 2(μ4-PO4)]X (X - I, PF6)",

abstract = "The first discrete organometallic tetranuclear μ4-PO 4 complex, [{(Cp*Cr)2(μ-OMe)2} 2(μ4-PO4)]+ (5; Cp* = η5-C5Me5), was isolated as the iodide and PF6 salts from the reaction between NaH2PO4 and [Cp*Cr(μ-OMe)I]2 (2), which was derived from thiolate methylation of [Cp*Cr{η3-HN(CH2CH 2S)2}] (1) with MeI in MeOH.",

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T2 - [{(Cp*Cr)2(μ-OMe)2} 2(μ4-PO4)]X (X - I, PF6)

AU - Shin, Richard Y.C.

AU - Tan, Geok Kheng

AU - Koh, Lip Lin

AU - Goh, Lai Yoong

AU - Webster, Richard D.

PY - 2005/3/28

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N2 - The first discrete organometallic tetranuclear μ4-PO 4 complex, [{(Cp*Cr)2(μ-OMe)2} 2(μ4-PO4)]+ (5; Cp* = η5-C5Me5), was isolated as the iodide and PF6 salts from the reaction between NaH2PO4 and [Cp*Cr(μ-OMe)I]2 (2), which was derived from thiolate methylation of [Cp*Cr{η3-HN(CH2CH 2S)2}] (1) with MeI in MeOH.

AB - The first discrete organometallic tetranuclear μ4-PO 4 complex, [{(Cp*Cr)2(μ-OMe)2} 2(μ4-PO4)]+ (5; Cp* = η5-C5Me5), was isolated as the iodide and PF6 salts from the reaction between NaH2PO4 and [Cp*Cr(μ-OMe)I]2 (2), which was derived from thiolate methylation of [Cp*Cr{η3-HN(CH2CH 2S)2}] (1) with MeI in MeOH.

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JO - Organometallics

JF - Organometallics

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An organometallic tetranuclear complex of μ₄-PO₄: [{(C_p*Cr)₂(μ-OMe)₂} ₂(μ₄-PO₄)]X (X - I, PF₆)

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