Anion-templated 2D frameworks from hexahydroxytriphenylene

Mahbod Morshedi; Anthony C. Willis; Nicholas G. White

doi:10.1039/c6ce00297h

Anion-templated 2D frameworks from hexahydroxytriphenylene

Mahbod Morshedi, Anthony C. Willis, Nicholas G. White^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Hexahydroxytriphenylene (HHTP) forms 2D frameworks through O-H⋯anion hydrogen bonds with a range of anions. In all cases, 1:1 co-crystals of HHTP and tetraalkylammonium·anion salts are obtained, which have a layered 2D structure. When HSO₄^- was used as anion, an unprecedented methylation reaction was observed giving crystals containing the methylsulfate anion (MeOSO₃^-).

Original language	English
Pages (from-to)	4281-4284
Number of pages	4
Journal	CrystEngComm
Volume	18
Issue number	23
DOIs	https://doi.org/10.1039/c6ce00297h
Publication status	Published - 2016

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abstract = "Hexahydroxytriphenylene (HHTP) forms 2D frameworks through O-H⋯anion hydrogen bonds with a range of anions. In all cases, 1:1 co-crystals of HHTP and tetraalkylammonium·anion salts are obtained, which have a layered 2D structure. When HSO4- was used as anion, an unprecedented methylation reaction was observed giving crystals containing the methylsulfate anion (MeOSO3-).",

author = "Mahbod Morshedi and Willis, {Anthony C.} and White, {Nicholas G.}",

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AB - Hexahydroxytriphenylene (HHTP) forms 2D frameworks through O-H⋯anion hydrogen bonds with a range of anions. In all cases, 1:1 co-crystals of HHTP and tetraalkylammonium·anion salts are obtained, which have a layered 2D structure. When HSO4- was used as anion, an unprecedented methylation reaction was observed giving crystals containing the methylsulfate anion (MeOSO3-).

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Anion-templated 2D frameworks from hexahydroxytriphenylene

Abstract

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