Arsenicin A, A natural polyarsenical: Synthesis and crystal structure

Di Lu; A. David Rae; Geoff Salem; Michelle L. Weir; Anthony C. Willis; S. Bruce Wild

doi:10.1021/om900998q

Arsenicin A, A natural polyarsenical: Synthesis and crystal structure

Di Lu, A. David Rae, Geoff Salem, Michelle L. Weir, Anthony C. Willis, S. Bruce Wild^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The synthesis of the natural polyarsenical Arsenicin A and its crystal structure are described. The molecule has the adamantane-type structure of arsenic trioxide in which three of the oxygen atoms have been replaced by methylene groups to generate four arsenic stereocenters of the same configuration in each enantiomer of the racemate.

Original language	English
Pages (from-to)	32-33
Number of pages	2
Journal	Organometallics
Volume	29
Issue number	1
DOIs	https://doi.org/10.1021/om900998q
Publication status	Published - 11 Jan 2010

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title = "Arsenicin A, A natural polyarsenical: Synthesis and crystal structure",

abstract = "The synthesis of the natural polyarsenical Arsenicin A and its crystal structure are described. The molecule has the adamantane-type structure of arsenic trioxide in which three of the oxygen atoms have been replaced by methylene groups to generate four arsenic stereocenters of the same configuration in each enantiomer of the racemate.",

author = "Di Lu and \{David Rae\}, A. and Geoff Salem and Weir, \{Michelle L.\} and Willis, \{Anthony C.\} and \{Bruce Wild\}, S.",

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AU - Lu, Di

AU - David Rae, A.

AU - Salem, Geoff

AU - Weir, Michelle L.

AU - Willis, Anthony C.

AU - Bruce Wild, S.

PY - 2010/1/11

Y1 - 2010/1/11

N2 - The synthesis of the natural polyarsenical Arsenicin A and its crystal structure are described. The molecule has the adamantane-type structure of arsenic trioxide in which three of the oxygen atoms have been replaced by methylene groups to generate four arsenic stereocenters of the same configuration in each enantiomer of the racemate.

AB - The synthesis of the natural polyarsenical Arsenicin A and its crystal structure are described. The molecule has the adamantane-type structure of arsenic trioxide in which three of the oxygen atoms have been replaced by methylene groups to generate four arsenic stereocenters of the same configuration in each enantiomer of the racemate.

UR - https://www.scopus.com/pages/publications/73649106171

U2 - 10.1021/om900998q

DO - 10.1021/om900998q

M3 - Article

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VL - 29

SP - 32

EP - 33

JO - Organometallics

JF - Organometallics

IS - 1

ER -

Arsenicin A, A natural polyarsenical: Synthesis and crystal structure

Abstract

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