Bi-and poly(carbyne) functionalised polycyclic aromatics

Benjamin J. Frogley; Anthony F. Hill; Antonia Seitz

doi:10.1039/d0cc00786b

Bi-and poly(carbyne) functionalised polycyclic aromatics

Benjamin J. Frogley, Anthony F. Hill^*, Antonia Seitz

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Complexes where a central polyaromatic ring system is substituted with one to four tungsten carbynes have been prepared by Pd⁰/Au^I-mediated coupling between a tungsten stannylcarbyne and aryl halides. This strategy enables preparation of complexes with one to three carbynes substituted onto a single phenyl ring, the first anthracenyl mono-and bis-carbynes, and a tetra(carbyne) complex constructed about a central pyrene ring system.

Original language	English
Pages (from-to)	3265-3268
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	22
DOIs	https://doi.org/10.1039/d0cc00786b
Publication status	Published - 18 Mar 2020

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abstract = "Complexes where a central polyaromatic ring system is substituted with one to four tungsten carbynes have been prepared by Pd0/AuI-mediated coupling between a tungsten stannylcarbyne and aryl halides. This strategy enables preparation of complexes with one to three carbynes substituted onto a single phenyl ring, the first anthracenyl mono-and bis-carbynes, and a tetra(carbyne) complex constructed about a central pyrene ring system.",

author = "Frogley, {Benjamin J.} and Hill, {Anthony F.} and Antonia Seitz",

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AU - Frogley, Benjamin J.

AU - Hill, Anthony F.

AU - Seitz, Antonia

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N2 - Complexes where a central polyaromatic ring system is substituted with one to four tungsten carbynes have been prepared by Pd0/AuI-mediated coupling between a tungsten stannylcarbyne and aryl halides. This strategy enables preparation of complexes with one to three carbynes substituted onto a single phenyl ring, the first anthracenyl mono-and bis-carbynes, and a tetra(carbyne) complex constructed about a central pyrene ring system.

AB - Complexes where a central polyaromatic ring system is substituted with one to four tungsten carbynes have been prepared by Pd0/AuI-mediated coupling between a tungsten stannylcarbyne and aryl halides. This strategy enables preparation of complexes with one to three carbynes substituted onto a single phenyl ring, the first anthracenyl mono-and bis-carbynes, and a tetra(carbyne) complex constructed about a central pyrene ring system.

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DO - 10.1039/d0cc00786b

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JF - Chemical Communications

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ER -

Bi-and poly(carbyne) functionalised polycyclic aromatics

Abstract

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