Bimetallic dihydrobis(methimazolyl)borate coordination: Structure [Mo 2{μ-H2B(mt)2}(CO)7][Au 2μ2-H2B(mt)2}](PEt 3)2] (mt = methimazolyl)

Anthony F. Hill; Matthew K. Smith; Never Tshabang; Anthony C. Willis

doi:10.1021/om900891a

Bimetallic dihydrobis(methimazolyl)borate coordination: Structure [Mo ₂{μ-H₂B(mt)₂}(CO)₇][Au ₂μ₂-H₂B(mt)₂}](PEt ₃)₂] (mt = methimazolyl)

Anthony F. Hill
, Matthew K. Smith
, Never Tshabang
, Anthony C. Willis

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The reaction of Na[H₂B(Mt)₂] (mt = methimazolyl) with [AuBr(PEt₃)] provides [Au{H₂B(mt)₂}(PEt ₃)], which reacts with [Mo(CO)₃(NCMe)₃] or [Mo(CO)₃(η⁶-C₇H₈)] to provide the bimetallic salt [Mo₂{μ₂H₂B(mt) ₂}(CO)₇][Au₂{,μ₂-H ₂B(mt)₂}](PEt3)2], featuring two distinct coordination modes for the H₂B(mt)₂ bridging ligands.

Original language	English
Pages (from-to)	473-477
Number of pages	5
Journal	Organometallics
Volume	29
Issue number	2
DOIs	https://doi.org/10.1021/om900891a
Publication status	Published - 25 Jan 2010

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title = "Bimetallic dihydrobis(methimazolyl)borate coordination: Structure [Mo 2\{μ-H2B(mt)2\}(CO)7][Au 2μ2-H2B(mt)2\}](PEt 3)2] (mt = methimazolyl)",

abstract = "The reaction of Na[H2B(Mt)2] (mt = methimazolyl) with [AuBr(PEt3)] provides [Au\{H2B(mt)2\}(PEt 3)], which reacts with [Mo(CO)3(NCMe)3] or [Mo(CO)3(η6-C7H8)] to provide the bimetallic salt [Mo2\{μ2H2B(mt) 2\}(CO)7][Au2\{,μ2-H 2B(mt)2\}](PEt3)2], featuring two distinct coordination modes for the H2B(mt)2 bridging ligands.",

author = "Hill, \{Anthony F.\} and Smith, \{Matthew K.\} and Never Tshabang and Willis, \{Anthony C.\}",

year = "2010",

month = jan,

day = "25",

doi = "10.1021/om900891a",

language = "English",

volume = "29",

pages = "473--477",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "2",

}

TY - JOUR

T1 - Bimetallic dihydrobis(methimazolyl)borate coordination

T2 - Structure [Mo 2{μ-H2B(mt)2}(CO)7][Au 2μ2-H2B(mt)2}](PEt 3)2] (mt = methimazolyl)

AU - Hill, Anthony F.

AU - Smith, Matthew K.

AU - Tshabang, Never

AU - Willis, Anthony C.

PY - 2010/1/25

Y1 - 2010/1/25

N2 - The reaction of Na[H2B(Mt)2] (mt = methimazolyl) with [AuBr(PEt3)] provides [Au{H2B(mt)2}(PEt 3)], which reacts with [Mo(CO)3(NCMe)3] or [Mo(CO)3(η6-C7H8)] to provide the bimetallic salt [Mo2{μ2H2B(mt) 2}(CO)7][Au2{,μ2-H 2B(mt)2}](PEt3)2], featuring two distinct coordination modes for the H2B(mt)2 bridging ligands.

AB - The reaction of Na[H2B(Mt)2] (mt = methimazolyl) with [AuBr(PEt3)] provides [Au{H2B(mt)2}(PEt 3)], which reacts with [Mo(CO)3(NCMe)3] or [Mo(CO)3(η6-C7H8)] to provide the bimetallic salt [Mo2{μ2H2B(mt) 2}(CO)7][Au2{,μ2-H 2B(mt)2}](PEt3)2], featuring two distinct coordination modes for the H2B(mt)2 bridging ligands.

UR - https://www.scopus.com/pages/publications/74549222236

U2 - 10.1021/om900891a

DO - 10.1021/om900891a

M3 - Article

SN - 0276-7333

VL - 29

SP - 473

EP - 477

JO - Organometallics

JF - Organometallics

IS - 2

ER -

Bimetallic dihydrobis(methimazolyl)borate coordination: Structure [Mo ₂{μ-H₂B(mt)₂}(CO)₇][Au ₂μ₂-H₂B(mt)₂}](PEt ₃)₂] (mt = methimazolyl)

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