Bis(triphenylphosphoranylidene)ammonium docosacarbonyl(μ8- phosphido)octaruthenate chloroform solvate

Michael D. Randles; Anthony C. Willis; Marie P. Cifuentes; Mark C. Humphrey

doi:10.1107/S1600536806034052

Bis(triphenylphosphoranylidene)ammonium docosacarbonyl(μ₈- phosphido)octaruthenate chloroform solvate

Michael D. Randles, Anthony C. Willis, Marie P. Cifuentes, Mark C. Humphrey^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title compound, (C₃₆H₃₀NP₂)[Ru ₈P(CO)₂₂]·CHCl₃ or [N(PPh ₃)₂][Ru₈(μ₈-P)(CO) ₂₂]·CHCl₃, comprises a square antiprismatic octaruthenium cluster anion with an interstitial phosphido ligand, two bridging carbonyl ligands, and 20 terminal carbonyl ligands, together with a disordered PPN cation and a disordered chloroform solvent molecule.

Original language	English
Pages (from-to)	m2350-m2351
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	9
DOIs	https://doi.org/10.1107/S1600536806034052
Publication status	Published - Sept 2006

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title = "Bis(triphenylphosphoranylidene)ammonium docosacarbonyl(μ8- phosphido)octaruthenate chloroform solvate",

abstract = "The title compound, (C36H30NP2)[Ru 8P(CO)22]·CHCl3 or [N(PPh 3)2][Ru8(μ8-P)(CO) 22]·CHCl3, comprises a square antiprismatic octaruthenium cluster anion with an interstitial phosphido ligand, two bridging carbonyl ligands, and 20 terminal carbonyl ligands, together with a disordered PPN cation and a disordered chloroform solvent molecule.",

author = "Randles, {Michael D.} and Willis, {Anthony C.} and Cifuentes, {Marie P.} and Humphrey, {Mark C.}",

year = "2006",

month = sep,

doi = "10.1107/S1600536806034052",

language = "English",

volume = "62",

pages = "m2350--m2351",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "9",

}

TY - JOUR

T1 - Bis(triphenylphosphoranylidene)ammonium docosacarbonyl(μ8- phosphido)octaruthenate chloroform solvate

AU - Randles, Michael D.

AU - Willis, Anthony C.

AU - Cifuentes, Marie P.

AU - Humphrey, Mark C.

PY - 2006/9

Y1 - 2006/9

N2 - The title compound, (C36H30NP2)[Ru 8P(CO)22]·CHCl3 or [N(PPh 3)2][Ru8(μ8-P)(CO) 22]·CHCl3, comprises a square antiprismatic octaruthenium cluster anion with an interstitial phosphido ligand, two bridging carbonyl ligands, and 20 terminal carbonyl ligands, together with a disordered PPN cation and a disordered chloroform solvent molecule.

AB - The title compound, (C36H30NP2)[Ru 8P(CO)22]·CHCl3 or [N(PPh 3)2][Ru8(μ8-P)(CO) 22]·CHCl3, comprises a square antiprismatic octaruthenium cluster anion with an interstitial phosphido ligand, two bridging carbonyl ligands, and 20 terminal carbonyl ligands, together with a disordered PPN cation and a disordered chloroform solvent molecule.

UR - http://www.scopus.com/inward/record.url?scp=33748542246&partnerID=8YFLogxK

U2 - 10.1107/S1600536806034052

DO - 10.1107/S1600536806034052

M3 - Article

SN - 1600-5368

VL - 62

SP - m2350-m2351

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 9

ER -

Bis(triphenylphosphoranylidene)ammonium docosacarbonyl(μ₈- phosphido)octaruthenate chloroform solvate

Abstract

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