Caveats for poly(methimazolyl)borate chemistry: The novel inorganic heterocycles [H2C(mt)2BR2]Cl (mt = methimazolyl; BR2 = BH2, BH(mt), 9-BBN)

Ian R. Crossley; Anthony F. Hill; Elizabeth R. Humphrey; Matthew K. Smith; Never Tshabang; Anthony C. Willis

doi:10.1039/b407733d

Caveats for poly(methimazolyl)borate chemistry: The novel inorganic heterocycles [H₂C(mt)₂BR₂]Cl (mt = methimazolyl; BR₂ = BH₂, BH(mt), 9-BBN)

Ian R. Crossley, Anthony F. Hill^*, Elizabeth R. Humphrey, Matthew K. Smith, Never Tshabang, Anthony C. Willis

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Whilst frequently used for reactions of poly(methimazolyl)borates, dichloromethane is not an innocent solvent, but rather slowly forms heterocyclic salts [H₂C(mt)₂BR₂]Cl, three examples of which (BR₂ = BH₂, BH(mt), 9-borabicyclononyl) have been structurally characterised to confirm the unprecedented B(NCS)₂C connectivity.

Original language	English
Pages (from-to)	1878-1879
Number of pages	2
Journal	Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/b407733d
Publication status	Published - 21 Aug 2004

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abstract = "Whilst frequently used for reactions of poly(methimazolyl)borates, dichloromethane is not an innocent solvent, but rather slowly forms heterocyclic salts [H2C(mt)2BR2]Cl, three examples of which (BR2 = BH2, BH(mt), 9-borabicyclononyl) have been structurally characterised to confirm the unprecedented B(NCS)2C connectivity.",

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AU - Crossley, Ian R.

AU - Hill, Anthony F.

AU - Humphrey, Elizabeth R.

AU - Smith, Matthew K.

AU - Tshabang, Never

AU - Willis, Anthony C.

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AB - Whilst frequently used for reactions of poly(methimazolyl)borates, dichloromethane is not an innocent solvent, but rather slowly forms heterocyclic salts [H2C(mt)2BR2]Cl, three examples of which (BR2 = BH2, BH(mt), 9-borabicyclononyl) have been structurally characterised to confirm the unprecedented B(NCS)2C connectivity.

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Caveats for poly(methimazolyl)borate chemistry: The novel inorganic heterocycles [H₂C(mt)₂BR₂]Cl (mt = methimazolyl; BR₂ = BH₂, BH(mt), 9-BBN)

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