Chemoenzymatic and enantiodivergent routes to highly functionalised steroidal nuclei

Martin G. Banwell; David C.R. Hockless; Jeffrey W. Holman; Robert W. Longmore; Kenneth J. McRae; Ha T.T. Pham

doi:10.1055/s-1999-2856

Chemoenzymatic and enantiodivergent routes to highly functionalised steroidal nuclei

Martin G. Banwell^*
, David C.R. Hockless
, Jeffrey W. Holman
, Robert W. Longmore
, Kenneth J. McRae
, Ha T.T. Pham

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The bromobenzene-derived and enantiopure cis-1,2-dihydrocatechol 2 can be elaborated, via Diels-Alder cycloaddition and anionic oxy-Cope rearrangement reactions, to either compound 1 or its enantiomer (ent-1).

Original language	English
Pages (from-to)	1491-1494
Number of pages	4
Journal	Synlett
Issue number	9
DOIs	https://doi.org/10.1055/s-1999-2856
Publication status	Published - 1999

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title = "Chemoenzymatic and enantiodivergent routes to highly functionalised steroidal nuclei",

abstract = "The bromobenzene-derived and enantiopure cis-1,2-dihydrocatechol 2 can be elaborated, via Diels-Alder cycloaddition and anionic oxy-Cope rearrangement reactions, to either compound 1 or its enantiomer (ent-1).",

keywords = "Anionic oxy-Cope rearrangement, Diels-Alder cycloaddition, Enantiodivergent synthesis, Steroids",

author = "Banwell, \{Martin G.\} and Hockless, \{David C.R.\} and Holman, \{Jeffrey W.\} and Longmore, \{Robert W.\} and McRae, \{Kenneth J.\} and Pham, \{Ha T.T.\}",

year = "1999",

doi = "10.1055/s-1999-2856",

language = "English",

pages = "1491--1494",

journal = "Synlett",

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publisher = "Georg Thieme Verlag",

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T1 - Chemoenzymatic and enantiodivergent routes to highly functionalised steroidal nuclei

AU - Banwell, Martin G.

AU - Hockless, David C.R.

AU - Holman, Jeffrey W.

AU - Longmore, Robert W.

AU - McRae, Kenneth J.

AU - Pham, Ha T.T.

PY - 1999

Y1 - 1999

N2 - The bromobenzene-derived and enantiopure cis-1,2-dihydrocatechol 2 can be elaborated, via Diels-Alder cycloaddition and anionic oxy-Cope rearrangement reactions, to either compound 1 or its enantiomer (ent-1).

AB - The bromobenzene-derived and enantiopure cis-1,2-dihydrocatechol 2 can be elaborated, via Diels-Alder cycloaddition and anionic oxy-Cope rearrangement reactions, to either compound 1 or its enantiomer (ent-1).

KW - Anionic oxy-Cope rearrangement

KW - Diels-Alder cycloaddition

KW - Enantiodivergent synthesis

KW - Steroids

UR - https://www.scopus.com/pages/publications/0032875337

U2 - 10.1055/s-1999-2856

DO - 10.1055/s-1999-2856

M3 - Article

SN - 0936-5214

SP - 1491

EP - 1494

JO - Synlett

JF - Synlett

IS - 9

ER -

Chemoenzymatic and enantiodivergent routes to highly functionalised steroidal nuclei

Abstract

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