Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide

Martin Banwell*, David Hockless, Bevyn Jarrott, Brian Kelly, Andrew Knill, Robert Longniore, Gregory Simpson

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    14 Citations (Scopus)

    Abstract

    The enantiopure dienes 8 and 24, which have been prepared by chemoenzymatic methods, engage in Diels-AIder cycloaddition reactions with maleic and citraconic anhydride to give adducts (e.g. 25-27) embodying the ABC-ring system associated with spinosyns A (1) and D (2).

    Original languageEnglish
    Pages (from-to)3555-3558
    Number of pages4
    JournalJournal of the Chemical Society, Perkin Transactions 1
    Issue number21
    DOIs
    Publication statusPublished - 2000

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