Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide

Martin Banwell; David Hockless; Bevyn Jarrott; Brian Kelly; Andrew Knill; Robert Longniore; Gregory Simpson

doi:10.1039/b006759h

Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide

Martin Banwell^*, David Hockless, Bevyn Jarrott, Brian Kelly, Andrew Knill, Robert Longniore, Gregory Simpson

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The enantiopure dienes 8 and 24, which have been prepared by chemoenzymatic methods, engage in Diels-AIder cycloaddition reactions with maleic and citraconic anhydride to give adducts (e.g. 25-27) embodying the ABC-ring system associated with spinosyns A (1) and D (2).

Original language	English
Pages (from-to)	3555-3558
Number of pages	4
Journal	Journal of the Chemical Society, Perkin Transactions 1
Issue number	21
DOIs	https://doi.org/10.1039/b006759h
Publication status	Published - 2000

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title = "Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide",

abstract = "The enantiopure dienes 8 and 24, which have been prepared by chemoenzymatic methods, engage in Diels-AIder cycloaddition reactions with maleic and citraconic anhydride to give adducts (e.g. 25-27) embodying the ABC-ring system associated with spinosyns A (1) and D (2).",

author = "Martin Banwell and David Hockless and Bevyn Jarrott and Brian Kelly and Andrew Knill and Robert Longniore and Gregory Simpson",

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AU - Banwell, Martin

AU - Hockless, David

AU - Jarrott, Bevyn

AU - Kelly, Brian

AU - Knill, Andrew

AU - Longniore, Robert

AU - Simpson, Gregory

PY - 2000

Y1 - 2000

N2 - The enantiopure dienes 8 and 24, which have been prepared by chemoenzymatic methods, engage in Diels-AIder cycloaddition reactions with maleic and citraconic anhydride to give adducts (e.g. 25-27) embodying the ABC-ring system associated with spinosyns A (1) and D (2).

AB - The enantiopure dienes 8 and 24, which have been prepared by chemoenzymatic methods, engage in Diels-AIder cycloaddition reactions with maleic and citraconic anhydride to give adducts (e.g. 25-27) embodying the ABC-ring system associated with spinosyns A (1) and D (2).

UR - https://www.scopus.com/pages/publications/0034619645

U2 - 10.1039/b006759h

DO - 10.1039/b006759h

M3 - Article

SN - 1472-7781

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EP - 3558

JO - Journal of the Chemical Society, Perkin Transactions 1

JF - Journal of the Chemical Society, Perkin Transactions 1

IS - 21

ER -

Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide

Abstract

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